This article surveys the relationship between ligand type, coordination geometry and metal
spin state in complexes of iron and other metal ions. Compounds and materials containing …

The capability of a given substance to change its spin state by the action of a stimulus, such
as a change in temperature, is by itself a very challenging property. Its interest is increased …

Here we report the first successful attempt to identify spin-crossover compounds in solutions
of metal complexes produced by mixing different ligands and an appropriate metal salt by …

The photoinduced properties of the octacoordinated complex K4MoIV (CN) 8⋅ 2 H2O were
studied by theoretical calculations, crystallography, and optical and magnetic …

The X-ray structure of 2-(dibromomethyl) benzonitrile, featuring unexpectedly short CN⋯ Br
halogen bond distances between a nitrile group and a C (sp3)-linked bromine atom, is …

The molecular design of spin‐crossover complexes relies on controlling the spin state of a
transition metal ion by proper chemical modifications of the ligands. Herein, the first N, N' …

This contribution reports on the recent developments concerning spin-crossover Fe (II) and
Fe (III) complexes of mononuclear nature. In the first section, the description of chemical …

In order to expand and exploit the useful properties of d6-iron (II) and d5-iron (III) complexes
in potential magnetic, photophysical, or magnetooptical applications, crucial ligand …

Here, we report a combined study of the effects of two chemical modifications to an N, N′-
disubstituted bis (pyrazol-3-yl) pyridine (3-bpp) and of different solvents on the spin …

Here we report two new ligands from a 2, 6‐bis (pyrazol‐3‐yl) pyridine family often used in
spin‐crossover research and their iron (II) and cobalt (II) complexes with the metal ion …