The incorporation of a synthetic, catalytically competent metallocofactor into a protein
scaffold to generate an artificial metalloenzyme (ArM) has been explored since the late …

The design of artificial catalysts able to compete with the catalytic proficiency of enzymes is
an intense subject of research. Non-covalent interactions are thought to be involved in …

Protein design is a valuable tool for understanding the fundamental factors that dictate
protein structure and function. The field of protein design has seen significant progress over …

In the field of asymmetric synthesis, nonracemic sulfoxides are recognized as valuable and
efficient reagents. Their extensive use as chiral auxiliaries and intermediates is …

Transition metal catalysts and enzymes possess unique and often complementary
properties that have made them important tools for chemical synthesis. The potential …

Designing an energy-efficient and cost-effective system for hydrogen (H 2) generation from
water or proton source remains as a challenge. Precious and rare earth metals such as …

Many efforts are being made in the design and engineering of metalloenzymes with catalytic
properties fulfilling the needs of practical applications. Progress in this field has recently …

Selective oxidation of sulfides was successfully performed by employing oxone (2KHSO5·
KHSO4· K2SO4) as oxidant without utilization of any catalyst/additive under mild reaction …

Artificial metalloenzymes have emerged as a promising approach to merge the attractive
properties of homogeneous catalysis and biocatalysis. The activity and selectivity, including …

Many bioinspired transition‐metal catalysts have been developed over the recent years. In
this review the progress in the design and application of ligand systems based on peptides …