Catalytic and mechanistic insights into the production of ethyl levulinate from biorenewable feedstocks

E Ahmad, MI Alam, KK Pant, MA Haider - Green Chemistry, 2016 - pubs.rsc.org
The importance of ethyl levulinate (EL) as a fuel additive and a potential biomass-derived
platform molecule is noteworthy. EL is obtained from the esterification of levulinic acid (LA) …

A perspective into ring-opening polymerization of ε-caprolactone and lactides: effect of, ligand, catalyst structure and system dynamics, on catalytic activity and …

WA Munzeiwa, BO Omondi, VO Nyamori - Polymer Bulletin, 2024 - Springer
Polylactic acid (PLAs) and polycaprolactones (PCLs) are emerging to be polyesters of
choice because they are biodegradable and biocompatible. The industrial viable method …

One-pot direct conversion of levulinic acid into high-yield valeric acid over a highly stable bimetallic Nb-Cu/Zr-doped porous silica catalyst

N Karanwal, D Verma, P Butolia, SM Kim, J Kim - Green Chemistry, 2020 - pubs.rsc.org
The direct conversion of levulinic acid (LA) to valeric biofuel is highly promising for the
development of biorefineries. Herein, LA is converted into valeric acid (VA) via one-pot direct …

Ru-Sn/AC for the aqueous-phase reduction of succinic acid to 1, 4-butanediol under continuous process conditions

DR Vardon, AE Settle, V Vorotnikov, MJ Menart… - ACS …, 2017 - ACS Publications
Succinic acid is a biomass-derived platform chemical that can be catalytically converted in
the aqueous phase to 1, 4-butanediol (BDO), a prevalent building block used in the polymer …

Bio-derived lactones–Combustion and exhaust emissions of a new class of renewable fuels

J Frost, P Hellier, N Ladommatos - Energy Conversion and Management, 2023 - Elsevier
The use of bioderived drop-in fuels is an essential step in the reduction in fossil fuel usage.
While ethanol and biodiesel are known quantities, the use of novel biomass that does not …

Role of Water on Zeolite-Catalyzed Dehydration of Polyalcohols and EVOH Polymer

HK Chau, QP Nguyen, AC Jerdy, DP Bui… - ACS …, 2023 - ACS Publications
Selective dehydration of polyalcohols over zeolites containing Brønsted acids is a promising
approach to purify and recycle multilayer polymer films consisting of non-polar polymers …

Mechanistic approaches toward rational design of a heterogeneous catalyst for ring-opening and deoxygenation of biomass-derived cyclic compounds

S Gupta, MI Alam, TS Khan… - … Sustainable Chemistry & …, 2019 - ACS Publications
Technologies for the processing of lignocellulosic biomass into fuels and chemicals are
generally focused on selective chemical transformation of the three different types of …

γ‐Valerolactone Enabling Spontaneously Inhibited Iodide Oxidation for High‐Quality Perovskite Single Crystal Fabrication

Z Li, S Sun, H Jiang, Z Ding, C Zhang… - Advanced Functional …, 2024 - Wiley Online Library
The iodide precursor oxidation has persistently plagued solution grown iodine‐based
perovskite single crystals (IPSCs) that inevitably introduce undesirable triiodide ion (I3−) …

Microkinetic analysis of ring opening and decarboxylation of γ-valerolactone over silica alumina

JQ Bond, CS Jungong, A Chatzidimitriou - Journal of Catalysis, 2016 - Elsevier
This study considers the thermochemistry and kinetics of γ-valerolactone and pentenoic acid
interconversion as well as the decarboxylation of both molecules over amorphous silica …

Development of 6-amyl-α-pyrone as a potential biomass-derived platform molecule

MI Alam, S Gupta, A Bohre, E Ahmad, TS Khan… - Green …, 2016 - pubs.rsc.org
Catalytic transformation routes for the valorization of biomass-derived 6-amyl-α-pyrone
(6PP) were explored for the first time. Ring-opening and decarboxylation of 6PP in water …