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Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆
Molecular magnetism has travelled a long way from the pioneering studies on electron
exchange and double exchange or spin crossover and valence tautomerism in small …
exchange and double exchange or spin crossover and valence tautomerism in small …
Recent progress on cyano-bridged transition-metal-based single-molecule magnets and single-chain magnets
JH Wang, ZY Li, M Yamashita, XH Bu - Coordination Chemistry Reviews, 2021 - Elsevier
Novel functional molecular-based magnetic materials, especially some members of the
Prussian blue family, have gained significant attention over the past few decades as they …
Prussian blue family, have gained significant attention over the past few decades as they …
Slow magnetization dynamics in a series of two-coordinate iron (II) complexes
A series of two-coordinate complexes of iron (II) were prepared and studied for single-
molecule magnet behavior. Five of the compounds, Fe [N (SiMe3)(Dipp)] 2 (1), Fe [C …
molecule magnet behavior. Five of the compounds, Fe [N (SiMe3)(Dipp)] 2 (1), Fe [C …
Single-molecule magnet engineering: building-block approaches
Tailoring the specific magnetic properties of any material relies on the topological control of
the constituent metal ion building blocks. Although this general approach does not seem to …
the constituent metal ion building blocks. Although this general approach does not seem to …
Controlled intramolecular electron transfers in cyanide-bridged molecular squares by chemical modifications and external stimuli
M Nihei, Y Sekine, N Suganami… - Journal of the …, 2011 - ACS Publications
A series of cyanide bridged Fe− Co molecular squares,[Co2Fe2 (CN) 6 (tp*) 2 (dtbbpy)
4](PF6) 2· 2MeOH (1),[Co2Fe2 (CN) 6 (tp*) 2 (bpy) 4](PF6) 2· 2MeOH (2), and [Co2Fe2 (CN) …
4](PF6) 2· 2MeOH (1),[Co2Fe2 (CN) 6 (tp*) 2 (bpy) 4](PF6) 2· 2MeOH (2), and [Co2Fe2 (CN) …
[PDF][PDF] A single-molecule-magnetic, cubane-based, triangular Co12 supercluster
MH Zeng, MX Yao, H Liang, WX Zhang… - … EDITION IN ENGLISH-, 2007 - labxing.com
For single-molecule magnet (SMM) behavior, molecular clusters require Ising
magnetoanisotropy (Dmol< 0) and a large ground-state spin multiplicity.[1] These …
magnetoanisotropy (Dmol< 0) and a large ground-state spin multiplicity.[1] These …
A Redox-Switchable Single-Molecule Magnet Incorporating [Re(CN)7]3-
DE Freedman, DM Jenkins, AT Iavarone… - Journal of the …, 2008 - ACS Publications
Reaction of [Re (CN) 7] 3-(S= 1/2) with 4 equiv of [(PY5Me2) Mn (MeCN)] 2+(S= 5/2) in
acetonitrile generates a blue solution containing the cyano-bridged cluster [(PY5Me2) …
acetonitrile generates a blue solution containing the cyano-bridged cluster [(PY5Me2) …
A Combination of Lacunary Polyoxometalates and High‐Nuclear Transition‐Metal Clusters under Hydrothermal Conditions. Part II: From Double Cluster, Dimer, and …
The hydrothermal reactions of trivacant Keggin A‐α‐XW9O34 polyoxoanions (X= PV/SiIV)
with transition‐metal ions (NiII/CuII/FeII) in the presence of amines result in eight novel high …
with transition‐metal ions (NiII/CuII/FeII) in the presence of amines result in eight novel high …
Trigonal antiprismatic Co (II) single molecule magnets with large uniaxial anisotropies: importance of Raman and tunneling mechanisms
The air-stable mononuclear Co (II) compounds [CoII (Tpm) 2][ClO4] 2 (1, Tpm= tris (pyrazol-
1-yl) methane),[CoII (Tpm) 2][BPh4] 2· 2MeCN (2) with trigonal antiprismatic geometry …
1-yl) methane),[CoII (Tpm) 2][BPh4] 2· 2MeCN (2) with trigonal antiprismatic geometry …
An Azophenine Radical-Bridged Fe2 Single-Molecule Magnet with Record Magnetic Exchange Coupling
One-electron reduction of the complex [(TPyA) 2FeII2 (NPhL2–)] 2+(TPyA= tris (2-
pyridylmethyl) amine, NPhLH2= azophenine= N, N′, N ″, N‴-tetraphenyl-2, 5-diamino-1 …
pyridylmethyl) amine, NPhLH2= azophenine= N, N′, N ″, N‴-tetraphenyl-2, 5-diamino-1 …