Generation of HO Radical from Hydrogen Peroxide Catalyzed by Aqua Complexes of the Group III Metals [M(H2O)n]3+ (M = Ga, In, Sc, Y, or La): A Theoretical …

AS Novikov, ML Kuznetsov, AJL Pombeiro… - ACS …, 2013 - ACS Publications
The mechanism of the rate-limiting stage of alkanes oxidation with hydrogen peroxide, that
is, formation of the hydroxyl radicals, catalyzed by aqua complexes,[M (H2O) n] 3+(1), of the …

Radical decomposition of hydrogen peroxide catalyzed by aqua complexes [M (H2O) n] 2+(M= Be, Zn, Cd)

ML Kuznetsov, FA Teixeira, NA Bokach… - Journal of catalysis, 2014 - Elsevier
The catalytic activity of the aqua complexes [M (H 2 O) n] 2+(1)(M= Be, n= 4; M= Zn, Cd, n=
6) toward the radical decomposition of H 2 O 2 and generation of the HO radical dot radicals …

Oxidation of olefins with hydrogen peroxide catalyzed by bismuth salts: A mechanistic study

ML Kuznetsov, BGM Rocha, AJL Pombeiro… - ACS …, 2015 - ACS Publications
Theoretical (DFT) calculations predict that soluble Bi salts exhibit catalytic activity toward
oxidation of olefins with H2O2. Reaction occurs via two competitive channels:(i) nonradical …

Sustainable chrome tanning system using protein-based product developed from leather waste: Wealth from waste

J Kanagaraj, RC Panda, R Prasanna - Polymer Bulletin, 2022 - Springer
Chrome tanning is one of the popular tanning methods followed globally that generates
considerable level of chromium pollution in the resulting effluent. The existing conventional …

Takovite-aluminosilicate@ MnFe2O4 nanocomposite, a novel magnetic adsorbent for efficient preconcentration of lead ions in food samples

ZS Kardar, MH Beyki, F Shemirani - Food Chemistry, 2016 - Elsevier
Here in we report preparation of MnFe 2 O 4 and magnetic takovite–aluminosilicate
adsorbent via precipitation methodology. The synthesized nanocomposite was applied in …

Synthesis of salicylaldehyde through oxidation of o-cresol: Evaluation of activity and selectivity of different metals supported on OMS-2 nanorods and kinetics

DS Pisal, GD Yadav - Molecular Catalysis, 2020 - Elsevier
Abstract Octahedral molecular sieve (OMS-2) was synthesized by the hydrothermal method
and modified by the impregnation of different metals to give M/OMS-2 catalysts (where M= V …

Hybrid materials based on bentonite functionalized with amine groups via the hydrolytic sol-gel method

TJ Gilberto, L Marçal, JM Silva, LA Rocha… - Journal of the Brazilian …, 2016 - SciELO Brasil
Bentonite is a natural clay that presents characteristics such as good capacity to exchange
cations, large specific surface area, large porosity, and possibility to undergo intercalation …

Water-soluble graft copolymer synthesized from collagenous waste and polyethylene glycol (PEG) with functional carboxylic chains: a highly efficient adsorbent for …

J Kanagaraj, RC Panda, V Sumathi - Industrial & Engineering …, 2015 - ACS Publications
A pragmatic pathway to zero emission is achieved by utilizing solid and liquid wastes
completely by recycling and generating value-added auxiliaries from chrome shaving waste …

Adsorption-based synthesis of environmentally friendly heterogeneous Chromium (III) catalysts for oxidation reactions into kaolinite, saponite, and their amine …

CA Vieira, BF Ferreira, AF da Silva… - ACS Applied Nano …, 2018 - ACS Publications
Batch experiments were used to evaluate the Brazilian São Simão kaolinite (Kao), the
Spanish Yuncillos saponite (Sa), and their derivatives organofunctionalized with 3 …

Synthesis of a graft-copolymer adsorbent through a green route and studies on its interactions with chromium (III) through active functional groups: kinetics and …

J Kanagaraj, RC Panda, V Sumathi - RSC Advances, 2015 - pubs.rsc.org
Chromium (III), a heavy metal, contributes towards pollution load, potentially even more than
the 2000 ppm level in the effluent of many industries. Managing chromium by means of …