Ultrafast dynamics of electrons and phonons: from the two-temperature model to the time-dependent Boltzmann equation

F Caruso, D Novko - Advances in Physics: X, 2022‏ - Taylor & Francis
The advent of pump-probe spectroscopy techniques paved the way to the exploration of
ultrafast dynamics of electrons and phonons in crystalline solids. Following photo-absorption …

[HTML][HTML] Non-adiabatic effects in elementary reaction processes at metal surfaces

M Alducin, RD Muiño, JI Juaristi - Progress in Surface Science, 2017‏ - Elsevier
Great success has been achieved in the modeling of gas-surface elementary processes by
the use of the Born-Oppenheimer approximation. However, in metal surfaces low energy …

Ab initio tensorial electronic friction for molecules on metal surfaces: Nonadiabatic vibrational relaxation

RJ Maurer, M Askerka, VS Batista, JC Tully - Physical Review B, 2016‏ - APS
Molecular adsorbates on metal surfaces exchange energy with substrate phonons and low-
lying electron-hole pair excitations. In the limit of weak coupling, electron-hole pair …

Symmetry-adapted high dimensional neural network representation of electronic friction tensor of adsorbates on metals

Y Zhang, RJ Maurer, B Jiang - The Journal of Physical Chemistry …, 2019‏ - ACS Publications
Nonadiabatic effects in chemical reaction at metal surfaces, due to excitation of electron–
hole pairs, stand at the frontier of the studies of gas-surface reaction dynamics. However, the …

Disentangling the role of electrons and phonons in the photoinduced CO desorption and CO oxidation on (O, CO)-Ru (0001)

A Tetenoire, JI Juaristi, M Alducin - Frontiers in Chemistry, 2023‏ - frontiersin.org
The role played by electronic and phononic excitations in the femtosecond laser induced
desorption and oxidation of CO coadsorbed with O on Ru (0001) is investigated using ab …

Surface electron density models for accurate ab initio molecular dynamics with electronic friction

D Novko, M Blanco-Rey, M Alducin, JI Juaristi - Physical Review B, 2016‏ - APS
Ab initio molecular dynamics with electronic friction (AIMDEF) is a valuable methodology to
study the interaction of atomic particles with metal surfaces. This method, in which the effect …

Photoinduced CO desorption dominates over oxidation on different O+ CO covered Ru (0001) surfaces

A Tetenoire, JI Juaristi, M Alducin - The Journal of Physical …, 2023‏ - ACS Publications
The photoinduced desorption and oxidation of CO on Ru (0001) is simulated using ab initio
molecular dynamics with electronic friction that accounts for the nonequilibrated excited …

Multicoverage Study of Femtosecond Laser-Induced Desorption of CO from Pd (111)

A S. Muzas, A Serrano Jiménez, Y Zhang… - The Journal of …, 2024‏ - ACS Publications
We study the strong coverage dependence of the femtosecond laser-induced desorption of
CO from Pd (111) using molecular dynamics simulations that consistently include the effect …

Femtosecond laser-induced desorption of hydrogen molecules from Ru (0001): A systematic study based on machine-learned potentials

S Lindner, I Lončarić, L Vrček… - The Journal of …, 2023‏ - ACS Publications
Femtosecond laser-induced dynamics of molecules on metal surfaces can be seamlessly
simulated with all nuclear degrees of freedom using ab initio molecular dynamics with …

Hot-electron effects during reactive scattering of H 2 from Ag (111): the interplay between mode-specific electronic friction and the potential energy landscape

Y Zhang, RJ Maurer, H Guo, B Jiang - Chemical science, 2019‏ - pubs.rsc.org
The breakdown of the Born–Oppenheimer approximation gives rise to nonadiabatic effects
in gas-surface reactions at metal surfaces. However, for a given reaction, it remains unclear …