Activation of H–H, Si–H, and C–H bonds through σ-bond coordination has grown in the past
30 years from a scientific curiosity to an important tool in the functionalization of …

The hydrogen evolution reaction (HER) has a key role in electrochemical water splitting.
Recently a lot of attention has been dedicated to HER from single atom catalysts (SACs) …

Conspectus The coordination of an element–element σ bond to a transition metal (TM) is
both a fundamentally intriguing binding mode and of critical importance to metal-mediated …

Huixiang Ang, Hui Teng Tan, Zhi Min Luo, Yu Zhang, Yuan Yuan Guo, Guilue Guo, Hua
Zhang, and Qingyu Yan* a highly positive Gibbs free energy of hydrogen absorption| Δ GH …

The nonclassical ruthenium hydride pincer complex [Ru (PNP)(H) 2 (H2)] 1 (PNP= 1, 3-bis
(di-tert-butyl-phosphinomethyl) pyridine) catalyzes the anti-Markovnikov addition of …

Well-defined iron bis (diphosphine) complexes are active catalysts for the dehydrogenative
C–H borylation of aromatic and heteroaromatic derivatives with pinacolborane. The …

The first chelating bis (N-heterocyclic silylene) xanthene ligand [SiII (Xant) SiII] as well as its
Ni complexes [SiII (Xant) SiII] Ni (η2-1, 3-cod) and [SiII (Xant) SiII] Ni (PMe3) 2 were …

For many years, it was believed that only transition-metal centers could activate small
molecules and enthalpically strong bonds. However, it has recently been shown that several …

There is a growing interest in considering the use of carbon dioxide as a carbon source,
because it is an abundant, cheap, and nontoxic molecule.[1] Recently, significant advances …

There have been a number of approaches developed for the catalyzed dehydrogenation of
amine–boranes as potential dihydrogen sources for hydrogen storage applications in recent …