In Situ UV–Vis–NIR Absorption Spectroscopy and Catalysis

ML Bols, J Ma, F Rammal, D Plessers, X Wu… - Chemical …, 2024 - ACS Publications
This review highlights in situ UV–vis–NIR range absorption spectroscopy in catalysis. A
variety of experimental techniques identifying reaction mechanisms, kinetics, and structural …

Tailoring bond microenvironments and reaction pathways of single‐atom catalysts for efficient water electrolysis

W Zheng, R Zhu, H Wu, T Ma, H Zhou… - Angewandte Chemie …, 2022 - Wiley Online Library
Single‐atom sites (SASs) are commonly stabilized and influenced by neighboring atoms in
the host; disclosing the structure–reactivity relationships of SASs in water electrolysis is one …

Boosting the electrocatalytic urea oxidation performance by amorphous–crystalline Ni-TPA@ NiSe heterostructures and mechanism discovery

L **, R Ji, H Wan, J He, P Gu, H Lin, Q Xu, J Lu - ACS Catalysis, 2022 - ACS Publications
Develo** cost-effective electrocatalysts and elucidating the in situ catalytic mechanism of
the urea oxidation reaction (UOR) is a cornerstone for develo** urea-based technology …

Unravelling the effects of active site density and energetics on the water oxidation activity of iridium oxides

C Liang, RR Rao, KL Svane, JHL Hadden, B Moss… - Nature Catalysis, 2024 - nature.com
Understanding what controls the reaction rate on iridium-based catalysts is central to
designing better electrocatalysts for the water oxidation reaction in proton exchange …

Electrocatalytic water oxidation with manganese phosphates

S Yang, K Yue, X Liu, S Li, H Zheng, Y Yan… - Nature …, 2024 - nature.com
As inspired by the Mn4CaO5 oxygen evolution center in nature, Mn-based electrocatalysts
have received overwhelming attention for water oxidation. However, the understanding of …

Engineering active sites on binary metal selenide heterointerface catalyst to boost urea electrooxidation

FO Boakye, MG Sendeku, A Kumar, S Ajmal… - Applied Catalysis B …, 2024 - Elsevier
Electrocatalytic urea oxidation reaction (UOR) with a low thermodynamic potential is a
perfect substitute for anodic oxygen evolution process (OER) in the effective generation of …

Single-atom iridium on hematite photoanodes for solar water splitting: Catalyst or spectator?

Q Guo, Q Zhao, R Crespo-Otero… - Journal of the …, 2023 - ACS Publications
Single-atom catalysts (SACs) on hematite photoanodes are efficient cocatalysts to boost
photoelectrochemical performance. They feature high atom utilization, remarkable activity …

Cooperative Effects Drive Water Oxidation Catalysis in Cobalt Electrocatalysts through the Destabilization of Intermediates

B Moss, KL Svane, D Nieto-Castro… - Journal of the …, 2024 - ACS Publications
A barrier to understanding the factors driving catalysis in the oxygen evolution reaction
(OER) is understanding multiple overlap** redox transitions in the OER catalysts. The …

Role of electrolyte pH on water oxidation for iridium oxides

C Liang, Y Katayama, Y Tao, A Morinaga… - Journal of the …, 2024 - ACS Publications
Understanding the effect of noncovalent interactions of intermediates at the polarized
catalyst–electrolyte interface on water oxidation kinetics is key for designing more active and …

Evaluating the stability of Ir single atom and Ru atomic cluster oxygen evolution reaction electrocatalysts

M Zlatar, D Nater, D Escalera-López, RM Joy… - Electrochimica …, 2023 - Elsevier
Single-atom catalysts (SACs) have recently emerged in electrocatalysis due to their
improved electrocatalytic performance in many industrially relevant reactions. The potential …