This Review compiles the evolution, mechanistic understanding, and more recent advances
in enantioselective Pd-catalyzed allylic substitution and decarboxylative and oxidative allylic …

The quest to find milder and more sustainable methods to generate highly reactive, carbon-
centred intermediates has led to a resurgence of interest in radical chemistry. In particular …

Compounds rich in sp3-hybridized carbons are desirable in drug discovery. Nickel-
catalyzed hydrocarbonation of alkenes is a potentially efficient method to synthesize these …

Conjugate addition is among the most important synthetic protocols for constructing carbon
skeletons and is widely used to synthesize natural products and drugs. However …

The stereocontrolled construction of C− C bonds remains one of the foremost challenges in
organic synthesis. At the heart of any chemical synthesis of a natural product or designed …

Fluorine has emerged as a “magic element” in medicinal chemistry, crop, and materials
science. 1 Although fluorine is the most abundant halogen in the earth's crust, it is contained …

The cooperation and interplay between organic and metal catalyst systems is of utmost
importance in nature and chemical synthesis. Here innovative and selective cooperative …

The metal-catalyzed asymmetric conjugate addition (ACA) reaction has emerged as a
general and powerful approach for the construction of optically active compounds and is …

This three volume book is the follow-up handbook to the bestselling volume" Metal-
Catalyzed Cross-Coupling Reactions", the definitive reference in the field. In line with the …

The direct application of carboxylic acids as a traceless activation group for radical Michael
additions has been accomplished via visible light-mediated photoredox catalysis. Photon …