Recent mechanistic developments in the field of controlled/living radical polymerization
(CRP) are reviewed. Particular emphasis is placed on structure–reactivity correlations and …

This review traces the development of addition–fragmentation chain transfer agents and
related ring-opening monomers highlighting recent innovation in these areas. The major …

The discovery of reversible-deactivation radical polymerization (RDRP) has provided an
avenue for the synthesis of a vast array of polymers with a rich variety of functionality and …

This paper provides a first update to the review of living radical polymerization achieved with
thiocarbonylthio compounds (ZC (= S) SR) by a mechanism of Reversible Addition …

The strength of multi-scale modeling to support the fundamental understanding and design
of radical polymerization processes is illustrated, considering both controlled and free …

We examine the reversible addition fragmentation chain transfer (RAFT) process with regard
to its potential and limits in future industrial applications (including those conducted on a …

The continuous amalgamation of photocatalysis into existing reversible deactivation radical
polymerisation (RDRP) processes has initiated a rapidly propagating area of polymer …

The thermodynamic stability of radicals as defined through isodesmic hydrogen transfer
reactions has been explored at a variety of theoretical levels. Radical stabilization energies …

This article is the first comprehensive review on the study and use of vinyl ester monomers in
reversible addition fragmentation chain transfer (RAFT) polymerization. It covers all the …

Carbamoyl fluorides, fluoroformates, and their analogues are a class of important
compounds and have been evidenced as versatile building blocks for the preparation of …