Iron catalysis in organic synthesis

I Bauer, HJ Knölker - Chemical reviews, 2015 - ACS Publications
The present review “Iron Catalysis in Organic Synthesis” covers the literature until the end of
June 2014 and represents a comprehensive update of a previous article published by Bolm …

First-row transition metal (de) hydrogenation catalysis based on functional pincer ligands

L Alig, M Fritz, S Schneider - Chemical reviews, 2018 - ACS Publications
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Organic synthesis with the most abundant transition metal–iron: from rust to multitasking catalysts

S Rana, JP Biswas, S Paul, A Paik… - Chemical Society Reviews, 2021 - pubs.rsc.org
In industries and academic laboratories, several late transition metal-catalyzed prerequisite
reactions are widely performed during single and multistep synthesis. However, besides the …

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

Catalytic (de) hydrogenation promoted by non-precious metals–Co, Fe and Mn: recent advances in an emerging field

GA Filonenko, R Van Putten, EJM Hensen… - Chemical Society …, 2018 - pubs.rsc.org
Catalytic hydrogenation and dehydrogenation reactions form the core of the modern
chemical industry. This vast class of reactions is found in any part of chemical synthesis …

Iron catalysis in reduction and hydrometalation reactions

D Wei, C Darcel - Chemical reviews, 2018 - ACS Publications
The last two decades have seen an impressive improvement of the use of iron as a
fascinating and valuable alternative transition metal in homogeneous catalysis in terms of …

Selective catalytic hydrogenations of nitriles, ketones, and aldehydes by well-defined manganese pincer complexes

S Elangovan, C Topf, S Fischer, H Jiao… - Journal of the …, 2016 - ACS Publications
Hydrogenations constitute fundamental processes in organic chemistry and allow for atom-
efficient and clean functional group transformations. In fact, the selective reduction of nitriles …

Hydride transfer reactions catalyzed by cobalt complexes

W Ai, R Zhong, X Liu, Q Liu - Chemical reviews, 2018 - ACS Publications
Cobalt has become increasingly attractive in homogeneous catalysis because of its unique
characteristics and outstanding catalytic performance in addition to being cheap and earth …

Nickel-catalyzed hydrogenative coupling of nitriles and amines for general amine synthesis

VG Chandrashekhar, W Baumann, M Beller… - Science, 2022 - science.org
Efficient and general methods for the synthesis of amines remain in high demand in the
chemical industry. Among the many known processes, catalytic hydrogenation is a cost …

Silica-supported Fe/Fe–O nanoparticles for the catalytic hydrogenation of nitriles to amines in the presence of aluminium additives

VG Chandrashekhar, T Senthamarai, RG Kadam… - Nature Catalysis, 2022 - nature.com
The hydrogenation of nitriles to amines represents an important and frequently used
industrial process due to the broad applicability of the resulting products in chemistry and life …