Advanced zeolite and ordered mesoporous silica-based catalysts for the conversion of CO 2 to chemicals and fuels

A Velty, A Corma - Chemical Society Reviews, 2023 - pubs.rsc.org
For many years, capturing, storing or sequestering CO2 from concentrated emission sources
or from air has been a powerful technique for reducing atmospheric CO2. Moreover, the use …

Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W **g, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Methane oxidation to methanol

NF Dummer, DJ Willock, Q He, MJ Howard… - Chemical …, 2022 - ACS Publications
The direct transformation of methane to methanol remains a significant challenge for
operation at a larger scale. Central to this challenge is the low reactivity of methane at …

Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Chemical loo**-based energy transformation via lattice oxygen modulated selective oxidation

Z Sun, CK Russell, KJ Whitty, EG Eddings, J Dai… - Progress in Energy and …, 2023 - Elsevier
Modulating anionic oxygen in metal oxides offers exceptional opportunities for energy
material synthesis via redox loo**; however, several challenges such as overoxidation …

Oxo dicopper anchored on carbon nitride for selective oxidation of methane

P **e, J Ding, Z Yao, T Pu, P Zhang, Z Huang… - Nature …, 2022 - nature.com
Selective conversion of methane (CH4) into value-added chemicals represents a grand
challenge for the efficient utilization of rising hydrocarbon sources. We report here dimeric …

Direct photo-oxidation of methane to methanol over a mono-iron hydroxyl site

B An, Z Li, Z Wang, X Zeng, X Han, Y Cheng… - Nature Materials, 2022 - nature.com
Natural gas, consisting mainly of methane (CH4), has a relatively low energy density at
ambient conditions (~ 36 kJ l− 1). Partial oxidation of CH4 to methanol (CH3OH) lifts the …

Nanozymes: activity origin, catalytic mechanism, and biological application

W Yang, X Yang, L Zhu, H Chu, X Li, W Xu - Coordination Chemistry …, 2021 - Elsevier
Nanozymes are nanomaterials with excellent enzyme-like characteristics. Compared with
natural enzymes, nanozymes possess significant advantages, such as low cost, high …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Direct conversion of methane with O2 at room temperature over edge-rich MoS2

J Mao, H Liu, X Cui, Y Zhang, X Meng, Y Zheng… - Nature Catalysis, 2023 - nature.com
Conversion of methane to value-added chemicals at low temperature by directly using
inexpensive O2 as oxidant offers an ideal route for methane utilization but remains a great …