A continuous shape measures analysis of the coordination polyhedra of a host of transition
metal complexes with bi-and multidentate ligands discloses the distortion pathway …

In molecular spin-crossover materials, the spin-state switching is strongly coupled with
changes in the structural degrees of freedom, which play a central role in the alteration of …

The spin-crossover phenomenon (SCO) is a fascinating field that potentially concerns any
material containing a (d4–d7) transition metal complex finding therefore an echo in as …

Molecules exhibiting bistability have been proposed as elementary binary units (bits) for
information storage, potentially enabling fast and efficient computing. In particular, transition …

The electronic structure relevant to low spin (LS)↔ high spin (HS) transitions in Fe (II)
coordination compounds with a FeN6 core are studied. The selected [Fe (tz) 6] 2+(1)(tz= 1H …

A series of four isostructural FeII2 complexes,[(TPyA) 2Fe2 (XL)] 2+(TPyA= tris (2-
pyridylmethyl) amine; XL2–= doubly deprotonated form of 3, 6-disubstituted-2, 5-dianilino-1 …

Spin-transition materials, including the families of spin-crossover and charge-transfer
systems, and more generally molecular-based materials exhibiting electronic and/or …

The spin-crossover compound [Fe (n-Bu-im) 3 (tren)](PF6) 2 shows an unusual long
relaxation time of 20 h after light-induced excited spin state trap** when irradiating at 80 …

The physical phenomenon of spin-crossover in molecular crystals is a multiscale process
whose properties rely on the supramolecular organization of the spin-crossover active …

Spin-transition materials can exhibit thermal hysteresis due to cooperative elastic
interactions in between active molecular sites. It results from the coupling of the …