Taming the cationic beast: novel developments in the synthesis and application of weakly coordinating anions
IM Riddlestone, A Kraft, J Schaefer… - Angewandte Chemie …, 2018 - Wiley Online Library
This Review gives a comprehensive overview of the most topical weakly coordinating
anions (WCAs) and contains information on WCA design, stability, and applications. As an …
anions (WCAs) and contains information on WCA design, stability, and applications. As an …
Artificial switchable catalysts
Catalysis is key to the effective and efficient transformation of readily available building
blocks into high value functional molecules and materials. For many years research in this …
blocks into high value functional molecules and materials. For many years research in this …
Crown ethers: sensors for ions and molecular scaffolds for materials and biological models
GW Gokel, WM Leevy, ME Weber - Chemical reviews, 2004 - ACS Publications
Crown ethers are heterocycles that, in their simplest form, are cyclic oligomers of dioxane.
The essential repeating unit of any simple crown ether is ethyleneoxy, ie,-CH2CH2O-, which …
The essential repeating unit of any simple crown ether is ethyleneoxy, ie,-CH2CH2O-, which …
Tunable and switchable catalysis enabled by cation-controlled gating with crown ether ligands
S Acosta-Calle, AJM Miller - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Catalysis has become an essential tool in science and technology, impacting
the discovery of pharmaceuticals, the manufacture of commodity chemicals and plastics, the …
the discovery of pharmaceuticals, the manufacture of commodity chemicals and plastics, the …
Spatiotemporal control for integrated catalysis
Integrated catalysis is an emerging methodology that can streamline the multi-step synthesis
of complicated products in a single reaction vessel, achieving a high degree of control and …
of complicated products in a single reaction vessel, achieving a high degree of control and …
Selecting double bond positions with a single cation-responsive iridium olefin isomerization catalyst
AM Camp, MR Kita, PT Blackburn… - Journal of the …, 2021 - ACS Publications
The catalytic transposition of double bonds holds promise as an ideal route to alkenes of
value as fragrances, commodity chemicals, and pharmaceuticals; yet, selective access to …
value as fragrances, commodity chemicals, and pharmaceuticals; yet, selective access to …
Cation-controlled catalysis with crown ether-containing transition metal complexes
Transition metal complexes that incorporate crown ethers into the supporting ligands have
emerged as a powerful class of catalysts capable of cation-tunable reactivity. Cations held in …
emerged as a powerful class of catalysts capable of cation-tunable reactivity. Cations held in …
Main group Lewis acid-mediated transformations of transition-metal hydride complexes
This Review highlights stoichiometric reactions and elementary steps of catalytic reactions
involving cooperative participation of transition-metal hydrides and main group Lewis acids …
involving cooperative participation of transition-metal hydrides and main group Lewis acids …
Incorporation of redox-inactive cations promotes iron catalyzed aerobic C–H oxidation at mild potentials
The synthesis and characterization of the Schiff base complexes Fe (II)(2M) and Fe (III) Cl
(3M), where M is a K+ or Ba2+ ion incorporated into the ligand, are reported. The Fe (III/II) …
(3M), where M is a K+ or Ba2+ ion incorporated into the ligand, are reported. The Fe (III/II) …
Customizing polymers by controlling cation switching dynamics in non-living polymerization
Controlling the chain growth process in non-living polymerization reactions is difficult
because chain termination typically occurs faster than the time it takes to apply an external …
because chain termination typically occurs faster than the time it takes to apply an external …