Taming the cationic beast: novel developments in the synthesis and application of weakly coordinating anions

IM Riddlestone, A Kraft, J Schaefer… - Angewandte Chemie …, 2018 - Wiley Online Library
This Review gives a comprehensive overview of the most topical weakly coordinating
anions (WCAs) and contains information on WCA design, stability, and applications. As an …

Artificial switchable catalysts

V Blanco, DA Leigh, V Marcos - Chemical Society Reviews, 2015 - pubs.rsc.org
Catalysis is key to the effective and efficient transformation of readily available building
blocks into high value functional molecules and materials. For many years research in this …

Crown ethers: sensors for ions and molecular scaffolds for materials and biological models

GW Gokel, WM Leevy, ME Weber - Chemical reviews, 2004 - ACS Publications
Crown ethers are heterocycles that, in their simplest form, are cyclic oligomers of dioxane.
The essential repeating unit of any simple crown ether is ethyleneoxy, ie,-CH2CH2O-, which …

Tunable and switchable catalysis enabled by cation-controlled gating with crown ether ligands

S Acosta-Calle, AJM Miller - Accounts of Chemical Research, 2023 - ACS Publications
Conspectus Catalysis has become an essential tool in science and technology, impacting
the discovery of pharmaceuticals, the manufacture of commodity chemicals and plastics, the …

Spatiotemporal control for integrated catalysis

S Deng, BJ Jolly, JR Wilkes, Y Mu, JA Byers… - Nature Reviews …, 2023 - nature.com
Integrated catalysis is an emerging methodology that can streamline the multi-step synthesis
of complicated products in a single reaction vessel, achieving a high degree of control and …

Selecting double bond positions with a single cation-responsive iridium olefin isomerization catalyst

AM Camp, MR Kita, PT Blackburn… - Journal of the …, 2021 - ACS Publications
The catalytic transposition of double bonds holds promise as an ideal route to alkenes of
value as fragrances, commodity chemicals, and pharmaceuticals; yet, selective access to …

Cation-controlled catalysis with crown ether-containing transition metal complexes

C Yoo, HM Dodge, AJM Miller - Chemical Communications, 2019 - pubs.rsc.org
Transition metal complexes that incorporate crown ethers into the supporting ligands have
emerged as a powerful class of catalysts capable of cation-tunable reactivity. Cations held in …

Main group Lewis acid-mediated transformations of transition-metal hydride complexes

A Maity, TS Teets - Chemical reviews, 2016 - ACS Publications
This Review highlights stoichiometric reactions and elementary steps of catalytic reactions
involving cooperative participation of transition-metal hydrides and main group Lewis acids …

Incorporation of redox-inactive cations promotes iron catalyzed aerobic C–H oxidation at mild potentials

T Chantarojsiri, JW Ziller, JY Yang - Chemical science, 2018 - pubs.rsc.org
The synthesis and characterization of the Schiff base complexes Fe (II)(2M) and Fe (III) Cl
(3M), where M is a K+ or Ba2+ ion incorporated into the ligand, are reported. The Fe (III/II) …

Customizing polymers by controlling cation switching dynamics in non-living polymerization

TV Tran, E Lee, YH Nguyen, HD Nguyen… - Journal of the American …, 2022 - ACS Publications
Controlling the chain growth process in non-living polymerization reactions is difficult
because chain termination typically occurs faster than the time it takes to apply an external …