Ion formation in MALDI mass spectrometry

R Zenobi, R Knochenmuss - Mass spectrometry reviews, 1998 - Wiley Online Library
The origin of ions in matrix‐assisted laser desorption/ionization (MALDI) mass spectrometry
is currently a matter of active research. A number of chemical and physical pathways have …

Effect of different solution flow rates on analyte ion signals in nano-ESI MS, or: when does ESI turn into nano-ESI?

A Schmidt, M Karas, T Dülcks - Journal of the American Society for Mass …, 2003 - Springer
In nano-ESI MS, the qualitative and quantitative characteristics of mass spectra vary
considerably upon the use of different spraying conditions, ie, aperture of the spraying …

Screening of lake sediments for emerging contaminants by liquid chromatography atmospheric pressure photoionization and electrospray ionization coupled to high …

AC Chiaia-Hernandez, M Krauss… - Environmental science & …, 2013 - ACS Publications
We developed a multiresidue method for the target and suspect screening of more than 180
pharmaceuticals, personal care products, pesticides, biocides, additives, corrosion …

Femtosecond real‐time probing of reactions. IX. Hydrogen‐atom transfer

JL Herek, S Pedersen, L Banares… - The Journal of chemical …, 1992 - pubs.aip.org
The real‐time dynamics of hydrogen‐atom‐transfer processes under collisionless conditions
are studied using femtosecond depletion techniques. The experiments focus on the methyl …

A dual experimental–theoretical perspective on ESPT photoacids and their challenges ahead

N Sülzner, G Jung, P Nuernberger - Chemical Science, 2025 - pubs.rsc.org
Photoacids undergo an increase in acidity upon electronic excitation, enabling excited-state
proton transfer (ESPT) reactions. A multitude of compounds that allow ESPT has been …

Enhanced photoacidities of cyanonaphthols

LM Tolbert, JE Haubrich - Journal of the American Chemical …, 1990 - ACS Publications
“Spectral and acidity data are for 1 X 4 M aqueous solutions. Lifetime data are in
Me2SO.'From absorption titration.“Calculated from emission maxima using the Forster cycle …

A combined spectroscopic and computational investigation on the solvent-to-chromophore excited-state proton transfer in the 2, 2′-pyridylbenzimidazole–methanol …

R Jarupula, S Khodia, M Shabeeb… - Physical Chemistry …, 2023 - pubs.rsc.org
This article demonstrates experimental proof of excited state 'solvent-to-chromophore'proton
transfer (ESPT) in the isolated gas phase PBI (2, 2′-pyridylbenzimidazole)–CH3OH …

Microhydration of PAH+ cations: evolution of hydration network in naphthalene+-(H 2 O) n clusters (n≤ 5)

K Chatterjee, O Dopfer - Chemical Science, 2018 - pubs.rsc.org
The interaction of polycyclic aromatic hydrocarbon molecules with water (H2O= W) is of
fundamental importance in chemistry and biology. Herein, size-selected microhydrated …

Reactivity of molecular clusters in the gas phase: proton-transfer reaction in neutral phenol-(ammonia) n and phenol-(ethanamine) n

C Jouvet, C Lardeux-Dedonder… - Journal of Physical …, 1990 - ACS Publications
Intermolecular charge-and proton-transfer processes, ie, the motion of proton associated
with the change of the electronic structure in hydrogen-bonded complexes, are of great …

Excited-state deactivation via solvent-to-chromophore proton transfer in an isolated 1: 1 molecular complex: experimental validation by measuring the energy barrier …

S Khodia, R Jarupula, S Baweja, M Shabeeb… - Physical Chemistry …, 2023 - pubs.rsc.org
We have experimentally demonstrated conclusive evidence of solvent-to-chromophore
excited-state proton transfer (ESPT) as a deactivation mechanism in a binary complex …