Nonaqueous polar solvents in reverse micelle systems

NM Correa, JJ Silber, RE Riter, NE Levinger - Chemical Reviews, 2012 - ACS Publications
2. BACKGROUND 2.1. Aqueous Reverse Micelles The unique properties of water including
its polarity and highly structured hydrogen bond network have led to the widespread use of …

Elucidating the speciation of extracted lanthanides by diglycolamides

AA Peroutka, SS Galley, JC Shafer - Coordination Chemistry Reviews, 2023 - Elsevier
Many studies over the past few decades have been devoted to addressing the application of
diglycolamides (DGAs) for hydrometallurgical-based, f-element separations. Work to date …

When is water not water? Exploring water confined in large reverse micelles using a highly charged inorganic molecular probe

B Baruah, JM Roden, M Sedgwick… - Journal of the …, 2006 - ACS Publications
The interior water pool of aerosol OT (AOT) reverse micelles tends toward bulk water
properties as the micelle size increases. Thus, deviations from bulk water behavior in large …

Synthesis and agglomeration of gold nanoparticles in reverse micelles

AP Herrera, O Resto, JG Briano, C Rinaldi - Nanotechnology, 2005 - iopscience.iop.org
Reverse micelles prepared in the system water, sodium bis-(2-ethylhexyl) sulfoccinate
(AOT), and isooctane were investigated as a templating system for the production of gold …

Dynamics of nanoscopic water: vibrational echo and infrared pump− probe studies of reverse micelles

IR Piletic, HS Tan, MD Fayer - The Journal of Physical Chemistry …, 2005 - ACS Publications
The dynamics of water in nanoscopic pools 1.7− 4.0 nm in diameter in AOT reverse micelles
were studied with ultrafast infrared spectrally resolved stimulated vibrational echo and …

The size of AOT reverse micelles

G Eskici, PH Axelsen - The Journal of Physical Chemistry B, 2016 - ACS Publications
Reverse micelles (RMs) made from water and sodium bis (2-ethylhexyl) sulfosuccinate
(AOT) are commonly studied experimentally as models of aqueous microenvironments …

Study on conductivity property and microstructure of TritonX-100/alkanol/n-heptane/water microemulsion

X Li, G He, W Zheng, G **ao - Colloids and Surfaces A: Physicochemical …, 2010 - Elsevier
The validity of percolation theories on TritonX-100/heptane/alkanol/water W/O (water-in-oil)
microemulsion has been investigated based on conductivity analysis. The experiment …

How to Characterize Amorphous Shapes: The Tale of a Reverse Micelle

CD Gale, M Derakhshani-Molayousefi… - The Journal of …, 2022 - ACS Publications
Aerosol-OT reverse micelles represent a chemical construct where surfactant molecules self-
assemble to stabilize water nanodroplets 1–10 nm in diameter. Although commonly …

Fourier transform infrared spectroscopy of azide ion in reverse micelles

Q Zhong, DA Steinhurst, EE Carpenter, JC Owrutsky - Langmuir, 2002 - ACS Publications
The antisymmetric stretching band of the ν 3 vibration of azide ion was studied in nanosize
water droplets confined in reverse micelles by Fourier transform infrared spectroscopy. In …

How the cation 1-butyl-3-methylimidazolium impacts the interaction between the entrapped water and the reverse micelle interface created with an ionic liquid-like …

CMO Lépori, NM Correa, JJ Silber, RD Falcone - Soft Matter, 2016 - pubs.rsc.org
The behavior of the interfacial water entrapped in reverse micelles (RMs) formed by the ionic
liquid-like surfactant 1-butyl-3-methylimidazolium 1, 4-bis-2-ethylhexylsulfosuccinate (bmim …