Design and applications of water-soluble coordination cages

EG Percástegui, TK Ronson, JR Nitschke - Chemical Reviews, 2020 - ACS Publications
Compartmentalization of the aqueous space within a cell is necessary for life. In similar
fashion to the nanometer-scale compartments in living systems, synthetic water-soluble …

Mesoionic and related less heteroatom-stabilized N-heterocyclic carbene complexes: synthesis, catalysis, and other applications

A Vivancos, C Segarra, M Albrecht - Chemical reviews, 2018 - ACS Publications
Mesoionic carbenes are a subclass of the family of N-heterocyclic carbenes that generally
feature less heteroatom stabilization of the carbenic carbon and hence impart specific donor …

Guest-driven self-assembly and chiral induction of photofunctional lanthanide tetrahedral cages

SJ Hu, XQ Guo, LP Zhou, DN Yan… - Journal of the …, 2022 - ACS Publications
Chiral luminescent lanthanide–organic cages have many potential applications in
enantioselective recognition, sensing, and asymmetric catalysis. However, due to the …

Supramolecular chirality in self-assembled systems

M Liu, L Zhang, T Wang - Chemical reviews, 2015 - ACS Publications
Chirality is a basic characteristic of living matter and nature. During the evolution of life on
our planet, nature has favored one kind of chirality, thereby selecting the l-amino acids (with …

Stimuli-responsive metal–ligand assemblies

AJ McConnell, CS Wood, PP Neelakandan… - Chemical …, 2015 - ACS Publications
Within living systems, molecular-scale responses to stimuli flow together into the intricate
and robust signal transduction networks that process information for an organism. Studies of …

Frontiers, Opportunities, and Challenges in Biochemical and Chemical Catalysis of CO2 Fixation

AM Appel, JE Bercaw, AB Bocarsly, H Dobbek… - Chemical …, 2013 - ACS Publications
Two major energy-related problems confront the world in the next 50 years. First, increased
worldwide competition for gradually depleting fossil fuel reserves (derived from past …

Metal–organic frameworks and self-assembled supramolecular coordination complexes: comparing and contrasting the design, synthesis, and functionality of metal …

TR Cook, YR Zheng, PJ Stang - Chemical reviews, 2013 - ACS Publications
In 1893, Alfred Werner described the structure of octahedral transition metal complexes and
provided the basis for assigning coordination number and oxidation state to what were then …

Molecular containers in complex chemical systems

S Zarra, DM Wood, DA Roberts… - Chemical Society Reviews, 2015 - pubs.rsc.org
Over the last decade molecular containers have been increasingly studied within the context
of complex chemical systems. Herein we discuss selected examples from the literature …

Water-soluble redox-active cage hosting polyoxometalates for selective desulfurization catalysis

LX Cai, SC Li, DN Yan, LP Zhou, F Guo… - Journal of the American …, 2018 - ACS Publications
Transformations within container-molecules provide a good alternative between traditional
homogeneous and heterogeneous catalysis, as the containers themselves can be regarded …

Fluorescent sensors: A bright future for cages

A Brzechwa-Chodzyńska, W Drożdż… - Coordination Chemistry …, 2021 - Elsevier
This review provides a general overview of the development of fluorescent chemosensors
based on closed three-dimensional architectures and highlights selected examples from …