Photocontrolled RAFT polymerization: past, present, and future

Y Lee, C Boyer, MS Kwon - Chemical Society Reviews, 2023 - pubs.rsc.org
In this review, we provide a brief history, progress, and applications, and discuss the
remaining challenges of photocontrolled reversible addition–fragmentation chain transfer …

Nitrogen-Centered Radicals in Functionalization of sp2 Systems: Generation, Reactivity, and Applications in Synthesis

C Pratley, S Fenner, JA Murphy - Chemical Reviews, 2022 - ACS Publications
The chemistry of nitrogen-centered radicals (NCRs) has plentiful applications in organic
synthesis, and they continue to expand as our understanding of these reactive species …

Photochemical and electrochemical applications of proton-coupled electron transfer in organic synthesis

PRD Murray, JH Cox, ND Chiappini, CB Roos… - Chemical …, 2021 - ACS Publications
We present here a review of the photochemical and electrochemical applications of multi-
site proton-coupled electron transfer (MS-PCET) in organic synthesis. MS-PCETs are redox …

[HTML][HTML] Recent advances in visible light-activated radical coupling reactions triggered by (i) ruthenium,(ii) iridium and (iii) organic photoredox agents

JD Bell, JA Murphy - Chemical Society Reviews, 2021 - pubs.rsc.org
Photoredox chemistry with organic or transition metal agents has been reviewed in earlier
years, but such is the pace of progress that we will overlap very little with earlier …

A light-driven enzymatic enantioselective radical acylation

Y Xu, H Chen, L Yu, X Peng, J Zhang, Z **ng, Y Bao… - Nature, 2024 - nature.com
Enzymes are recognized as exceptional catalysts for achieving high stereoselectivities,–, but
their ability to control the reactivity and stereoinduction of free radicals lags behind that of …

Organic thermally activated delayed fluorescence (TADF) compounds used in photocatalysis

MA Bryden, E Zysman-Colman - Chemical Society Reviews, 2021 - pubs.rsc.org
Organic compounds that show Thermally Activated Delayed Fluorescence (TADF) have
become wildly popular as next-generation emitters in organic light emitting diodes (OLEDs) …

Recent development of aryl diazonium chemistry for the derivatization of aromatic compounds

F Mo, D Qiu, L Zhang, J Wang - Chemical Reviews, 2021 - ACS Publications
Aryl diazonium salts are versatile building blocks in organic synthesis. In light of the ever-
increasing importance of aryl diazonium salts spanning most disciplines of the chemical …

Recent advances of 1, 2, 3, 5-tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN) in photocatalytic transformations

TY Shang, LH Lu, Z Cao, Y Liu, WM He… - Chemical …, 2019 - pubs.rsc.org
1, 2, 3, 5-Tetrakis (carbazol-9-yl)-4, 6-dicyanobenzene (4CzIPN) is a typical donor–acceptor
fluorophore, with carbazolyl as an electron donor and dicyanobenzene as an electron …

Visible light-induced organophotoredox-catalyzed difunctionalization of alkenes and alkynes

S Gupta, A Kundu, S Ghosh, A Chakraborty… - Green Chemistry, 2023 - pubs.rsc.org
In the era of organic synthesis, the direct difunctionalization strategies of alkenes and
alkynes are very eminent, which open up an excellent route to introduce two functional …

Mechanistic studies in photocatalysis

L Buzzetti, GEM Crisenza… - Angewandte Chemie …, 2019 - Wiley Online Library
The fast‐moving fields of photoredox and photocatalysis have recently provided fresh
opportunities to expand the potential of synthetic organic chemistry. Advances in light …