Strategies to generate nitrogen-centered radicals that may rely on photoredox catalysis: development in reaction methodology and applications in organic synthesis
For more than 70 years, nitrogen-centered radicals have been recognized as potent
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
synthetic intermediates. This review is a survey designed for use by chemists engaged in …
Photoredox-catalyzed C–H functionalization reactions
N Holmberg-Douglas, DA Nicewicz - Chemical reviews, 2021 - ACS Publications
The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …
interest and utility in the past several decades. Many different scientific disciplines have …
A toolbox approach to construct broadly applicable metal-free catalysts for photoredox chemistry: deliberate tuning of redox potentials and importance of halogens in …
E Speckmeier, TG Fischer, K Zeitler - Journal of the American …, 2018 - ACS Publications
The targeted choice of specific photocatalysts has been shown to play a critical role for the
successful realization of challenging photoredox catalytic transformations. Herein, we …
successful realization of challenging photoredox catalytic transformations. Herein, we …
Organic semiconductor photocatalyst can bifunctionalize arenes and heteroarenes
Photoexcited electron-hole pairs on a semiconductor surface can engage in redox reactions
with two different substrates. Similar to conventional electrosynthesis, the primary redox …
with two different substrates. Similar to conventional electrosynthesis, the primary redox …
Recent advances in radical C–H activation/radical cross-coupling
Research and industrial interest in radical C–H activation/radical cross-coupling chemistry
has continuously grown over the past few decades. These reactions offer fascinating and …
has continuously grown over the past few decades. These reactions offer fascinating and …
Organic photoredox catalysis
In this review, we highlight the use of organic photoredox catalysts in a myriad of synthetic
transformations with a range of applications. This overview is arranged by catalyst class …
transformations with a range of applications. This overview is arranged by catalyst class …
Organocatalysis in inert C–H bond functionalization
Y Qin, L Zhu, S Luo - Chemical reviews, 2017 - ACS Publications
As two coexisting and fast-growing research fields in modern synthetic chemistry, the
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …
merging of organocatalysis and C–H bond functionalization is well foreseeable, and the joint …
Recent advances in twisted intramolecular charge transfer (TICT) fluorescence and related phenomena in materials chemistry
Twisted intramolecular charge transfer (TICT) is an electron transfer process that occurs
upon photoexcitation in molecules that usually consist of a donor and acceptor part linked by …
upon photoexcitation in molecules that usually consist of a donor and acceptor part linked by …
Photocatalysis in organic and polymer synthesis
This review, with over 600 references, summarizes the recent applications of photoredox
catalysis for organic transformation and polymer synthesis. Photoredox catalysts are metallo …
catalysis for organic transformation and polymer synthesis. Photoredox catalysts are metallo …
Recent applications of organic dyes as photoredox catalysts in organic synthesis
DA Nicewicz, TM Nguyen - Acs Catalysis, 2014 - ACS Publications
Single electron redox pathways play a pivotal role in a vast array of processes integral to life
on the planet. It is no surprise that organic chemists have been intrigued by the possibility …
on the planet. It is no surprise that organic chemists have been intrigued by the possibility …