Asymmetric organocatalytic oxidations have been witnessed to an impressive development
in the last years thanks to the establishment of important chiral hypervalent iodines (III/V) …

The principle of vinylogy states that the electronic effects of a functional group in a molecule
are possibly transmitted to a distal position through interposed conjugated multiple bonds …

Strategies for achieving asymmetric catalysis with azaarenes have traditionally fallen short
of accomplishing remote stereocontrol, which would greatly enhance accessibility to distinct …

Abstract Due to the competing 1, 4‐addition reactions and the distance from the chirality
information, the construction of a remote stereogenic center via 1, 6‐addition reactions is …

Diarylprolinol silyl ethers are among the most utilized stereoselective organocatalysts for the
construction of complex molecules. With their debut in 2005, these catalysts have been …

A widely applicable, practical, and scalable synthetic method for efficient ene‐type double
oxidation of alkenes is reported via a two‐step alkenyl thianthrenium umpolung/Kornblum …

A facile, site‐selective, and divergent approach to construct 2‐aminopyrroles and quinoline‐
fused polyazaheterocycles enabled by a simple gold (III) catalyst from ynamides and …

The secondary amine‐catalyzed reactions proceeding via α, β‐unsaturated iminiums and
the N‐heterocyclic carbene (NHC)‐catalyzed transformations taking place via α, β …

Compared to γ‐addition, the α‐addition of α‐branched β, γ‐unsaturated aldehydes faces
larger steric hindrance and disrupts the π–π conjugation, which might be why very few …

N-Heterocyclic carbenes (NHCs) have emerged as powerful organocatalysts in controlling
the stereoselectivities of the reaction sites that are remote from the catalyst-binding position …