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Anti-Markovnikov intermolecular hydroamination of alkenes and alkynes: a mechanistic view
Hydroamination, the addition of an N–H bond across a C–C multiple bond, is a reaction with
a great synthetic potential. Important advances have been made in the last decades …
a great synthetic potential. Important advances have been made in the last decades …
Mn-, Fe-, and Co-catalyzed radical hydrofunctionalizations of olefins
Cofactor-mimetic aerobic oxidation has conceptually merged with catalysis of syngas
reactions to form a wide range of Markovnikov-selective olefin radical …
reactions to form a wide range of Markovnikov-selective olefin radical …
Bio-based amines through sustainable heterogeneous catalysis
The production of amines from biomass is a growing field of interest. Particularly the
amination of bio-based alcohols receives a lot of attention. In this review, we discuss recent …
amination of bio-based alcohols receives a lot of attention. In this review, we discuss recent …
Hydroamination: direct addition of amines to alkenes and alkynes
Nitrogen-containing compounds, such as amines, enamines, and imines, are valuable and
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …
commercially important bulk chemicals, specialty chemicals, and pharmaceuticals. 1 Among …
Enantio-and regioselective CuH-catalyzed hydroamination of alkenes
A highly enantio-and regioselective copper-catalyzed hydroamination reaction of alkenes
has been developed using diethoxymethylsilane and esters of hydroxylamines. The process …
has been developed using diethoxymethylsilane and esters of hydroxylamines. The process …
Catalytic carbophilic activation: catalysis by platinum and gold π acids
The ability of platinum and gold catalysts to effect powerful atom‐economic transformations
has led to a marked increase in their utilization. The quite remarkable correlation of their …
has led to a marked increase in their utilization. The quite remarkable correlation of their …
Hydrazines and azides via the metal-catalyzed hydrohydrazination and hydroazidation of olefins
The discovery, study, and implementation of the Co-and Mn-catalyzed hydrohydrazination
and hydroazidation reactions of olefins are reported. These reactions are equivalent to direct …
and hydroazidation reactions of olefins are reported. These reactions are equivalent to direct …
A Rh‐Catalyzed C− H Insertion Reaction for the Oxidative Conversion of Carbamates to Oxazolidinones
CG Espino, J Du Bois - Angewandte Chemie, 2001 - Wiley Online Library
Vicinal amino alcohols are common structural units in both naturally occurring molecules
and pharmaceutical agents.[1] These groups also appear as auxiliaries in asymmetric …
and pharmaceutical agents.[1] These groups also appear as auxiliaries in asymmetric …
More sustainable approaches for the synthesis of N-based heterocycles
More Sustainable Approaches for the Synthesis of N-Based Heterocycles | Chemical
Reviews Recently Viewedclose modal ACS ACS Publications C&EN CAS Find my …
Reviews Recently Viewedclose modal ACS ACS Publications C&EN CAS Find my …
Coordination chemistry of ene-1, 1-diamines and a prototype" Carbodicarbene"
General: All reactions were carried out in flame-dried glassware under Ar. The solvents were
purified by distillation over the drying agents indicated and were transferred under Ar. THF …
purified by distillation over the drying agents indicated and were transferred under Ar. THF …