As the “chemical chameleon”, sulfonyl-containing compounds and their variants have been
merged with various types of reactions for the efficient construction of diverse molecular …

Due to their unique properties, fluorinated scaffolds are pivotal compounds in
pharmaceuticals, agrochemicals, and materials science. Over the last years, the …

Herein, we report a method for C3-selective C–H tri-and difluoromethylthiolation of
pyridines. The method relies on borane-catalyzed pyridine hydroboration for generation of …

A photocatalytic approach for the C (sp3)–H trifluoromethylthiolation of amides under mild
reaction conditions is reported. We have developed a protocol that tolerates a large range of …

Direct C–H bond functionalization chemistry allows the pot-, atom-, and step-economical
and original construction of carbon–carbon and carbon-heteroatom bonds starting from …

A metal-free method for the vicinal thiosulfonylation of unactivated alkenes with
thiosulfonates using 9-mesityl-10-methylacridinium perchlorate as the photo-organocatalyst …

The review aims at providing an overview on the developments made in hydrogenation
reactions of molecules having various fluorinated groups (F, CF3, CF2H, CF2Rf). Indeed, the …

The synthetic strategies towards thiosulfonates (RSO2SR1) are comprehensively reviewed
from their original discovery to recent advances. Incorporation of the green credentials of the …

Conspectus Recently, the strategic installation of a fluorine atom or a fluoroalkyl group site-
selectively at the specific position of the target molecule has become a routine approach and …

A synergetic copper/photoredox catalyzed ATRA of styrenes and thiosulfonates is
developed. Besides aryl ethylenes, the challenging α-substituted styrenes were employed to …