Metal–organic cages are versatile supramolecular architectures, fulfilling various distinct
roles in the mediation of catalysed chemical reactions. M n L2 n cages have become …

Amino acids provide a convenient, economical, and non-toxic route for the synthesis of
chiral metallosupramolecular architectures, including coordination cages and metal–organic …

Helical molecular assemblies have been widely created so far, taking inspiration from
helical bioconstructs (eg, DNAs and proteins). However, the host utilities of such synthetic …

Molecular cages have promising host–guest properties for drug delivery applications.
Specifically, guest⊂ cage complexes can be used for the on-command release of …

Molecular cages are preorganized molecules with a central cavity, typically formed through
the reaction of their building blocks through chemical bonds. This requires, in most cases …

Heteroleptic (mixed‐ligand) coordination cages are of interest as host systems with more
structurally and functionally complex cavities than homoleptic architectures. The design of …

Metal–organic cages (MOCs) are discrete supramolecular entities consisting of metal nodes
and organic connectors or linkers; MOCs are noted for their high porosity and processability …

Oligoprolines adopt the well‐defined polyproline II (PPII) helical conformation, even at a
short chain length of six residues. These rigid peptides are versatile molecular rulers and …

The rational and controlled synthesis of metallo‐organic cages using polyaromatic ligands is
well established in the literature. There is a strong interest to advance this field towards the …

The self-assembly of metal-organic cages enables the rapid creation of atomically defined,
three-dimensional, nanoscale architectures from easily accessible building blocks. Rigid …