The use of two or more metal catalysts in a reaction is a powerful synthetic strategy to access
complex targets efficiently and selectively from simple starting materials. While capable of …

The coupling of aryl or vinyl halides with terminal acetylenes catalysed by palladium and
other transition metals, commonly termed as Sonogashira cross-coupling reaction, is one of …

Synthetic chemists are constantly challenged to consider more environmentally benign
methods for generation of the desired target molecules. 1 Recently, there has been an …

The transition metal-catalysed direct functionalisation of C–H bonds is an increasingly viable
alternative to the multi-step strategies traditionally adopted. The use of powerful and …

For organic chemists, the construction of C C bonds is the most essential aspect of the
assembly of molecules. Transition‐metal‐catalyzed coupling reactions have evolved as one …

The Sonogashira coupling reaction is not catalyzed by AuI/dppe in the absence of Pd
complexes. However, addition of 0.1 mol% of Pd (0) led to efficient cross-coupling reactions …

Bimetallic catalysis refers to homogeneous processes in which either two transition metals
(TM), or one TM and one Group 11 (G11) element (occasionally Hg also), cooperate in a …

Cross‐coupling is a powerful tool for the rapid construction of highly valuable compounds. In
this area of chemical transformations, new catalysts have recently emerged. Combining both …

Using two transition metals to simultaneously catalyze a reaction can offer distinct
opportunities for reactivity and selectivity when compared to using single-metal catalyst …

Two substrates containing an aryl iodide and an allenoate ester were prepared and the gold‐
induced cycloisomerisation to vinylgold (I) species and their proto‐deauration as well as the …