Atomically precise graphene nanoribbons: interplay of structural and electronic properties

RSK Houtsma, J de la Rie, M Stöhr - Chemical Society Reviews, 2021 - pubs.rsc.org
Graphene nanoribbons hold great promise for future applications in nanoelectronic devices,
as they may combine the excellent electronic properties of graphene with the opening of an …

Surface-activated coupling reactions confined on a surface

L Dong, PN Liu, N Lin - Accounts of chemical research, 2015 - ACS Publications
Conspectus Chemical reactions may take place in a pure phase of gas or liquid or at the
interface of two phases (gas–solid or liquid–solid). Recently, the emerging field of “surface …

On‐surface synthesis of atomically precise graphene nanoribbons

L Talirz, P Ruffieux, R Fasel - Advanced materials, 2016 - Wiley Online Library
The surface‐assisted polymerization and cyclodehydrogenation of specifically designed
organic precursors provides a route toward atomically precise graphene nanoribbons, which …

On-surface synthesis of rylene-type graphene nanoribbons

H Zhang, H Lin, K Sun, L Chen… - Journal of the …, 2015 - ACS Publications
The narrowest armchair graphene nanoribbon (AGNR) with five carbons across the width of
the GNR (5-AGNR) was synthesized on Au (111) surfaces via sequential dehalogenation …

Homo-coupling of terminal alkynes on a noble metal surface

YQ Zhang, N Kepčija, M Kleinschrodt, K Diller… - Nature …, 2012 - nature.com
The covalent linking of acetylenes presents an important route for the fabrication of novel
carbon-based scaffolds and two-dimensional materials distinct from graphene. To date few …

Mechanisms of halogen-based covalent self-assembly on metal surfaces

J Bjork, F Hanke, S Stafstrom - Journal of the American Chemical …, 2013 - ACS Publications
We computationally study the reaction mechanisms of halogen-based covalent self-
assembly, a major route for synthesizing molecular nanostructures and nanographenes on …

π-Electron conjugation in two dimensions

R Gutzler, DF Perepichka - Journal of the American Chemical …, 2013 - ACS Publications
Organic oligomers and polymers with extended π-conjugation are the fundamental building
blocks of organic electronic devices. Novel routes are being explored to create tailor-made …

Single-molecule resolution of an organometallic intermediate in a surface-supported Ullmann coupling reaction

W Wang, X Shi, S Wang, MA Van Hove… - Journal of the American …, 2011 - ACS Publications
We have studied the organometallic intermediate of a surface-supported Ullmann coupling
reaction from 4, 4 ″-dibromo-p-terphenyl to poly (para-phenylene) by scanning tunneling …

Insight into organometallic intermediate and its evolution to covalent bonding in surface-confined Ullmann polymerization

M Di Giovannantonio, M El Garah, J Lipton-Duffin… - ACS …, 2013 - ACS Publications
We provide insight into surface-catalyzed dehalogenative polymerization, analyzing the
organometallic intermediate and its evolution into planar polymeric structures. A combined …

Surface‐assisted organic synthesis of hyperbenzene nanotroughs

Q Fan, C Wang, Y Han, J Zhu… - Angewandte Chemie …, 2013 - Wiley Online Library
The surface-assisted synthesis of organic molecules and nanostructures is a promising
bottom-up approach towards functional surfaces for applications in catalysis, sensor …