A robust model for pore-water chemistry of clayrock

EC Gaucher, C Tournassat, FJ Pearson, P Blanc… - … et Cosmochimica Acta, 2009 - Elsevier
The chemistry of pore water is an important property of clayrocks being considered as host
rocks for long-term storage of radioactive waste. It may be difficult, if not impossible, to obtain …

Unlocking the potential of underground hydrogen storage for clean energy solutions

C Dodangoda, PG Ranjith, A Haque - … and Geophysics for Geo-Energy and …, 2024 - Springer
This review paper provides a critical examination of underground hydrogen storage (UHS)
as a viable solution for large-scale energy storage, surpassing 10 GWh capacities, and …

Mössbauer spectrometry insights into the redox reactivity of Fe-bearing phases in the environment

L Charlet, C Tournassat, JM Grenèche… - Journal of Materials …, 2023 - Springer
Rates and mechanisms of important reactions in the cycling of electrons via the geochemical
transformations of iron have been identified using Mössbauer spectrometry. The cycling of …

Anoxic nitrate reduction coupled with iron oxidation and attenuation of dissolved arsenic and phosphate in a sand and gravel aquifer

RL Smith, DB Kent, DA Repert, JK Böhlke - Geochimica et Cosmochimica …, 2017 - Elsevier
Nitrate has become an increasingly abundant potential electron acceptor for Fe (II) oxidation
in groundwater, but this redox couple has not been well characterized within aquifer …

Diffusive transport and reaction in clay rocks: A storage (nuclear waste, CO2, H2), energy (shale gas) and water quality issue

L Charlet, P Alt-Ep**, P Wersin, B Gilbert - Advances in Water Resources, 2017 - Elsevier
Clay rocks are low permeability sedimentary formations that provide records of Earth history,
influence the quality of water resources, and that are increasingly used for the extraction or …

Corrosion of carbon steel under sequential aerobic–anaerobic environmental conditions

H El Hajj, A Abdelouas, Y El Mendili, G Karakurt… - Corrosion …, 2013 - Elsevier
We investigated sequential aerobic and anaerobic microbiologically induced corrosion of
carbon steel to simulate deep geological disposal conditions. Under limited oxygen supply …

Water vapour sorption on mudrocks

T Seemann, P Bertier, BM Krooss… - … Society, London, Special …, 2017 - lyellcollection.org
High-resolution water sorption isotherms were measured on 13 representative mudrock
samples in order to assess the mechanisms of water vapour sorption and their relationship …

[HTML][HTML] A non-isothermal reactive transport model of the long-term geochemical evolution at the disposal cell scale in a HLW repository in granite

L Montenegro, J Samper, A Mon, L De Windt… - Applied Clay …, 2023 - Elsevier
The assessment of the long-term performance of the engineered barrier systems of high-
level radioactive waste (HLW) repositories requires the use of reactive transport models …

Anodic activation of iron corrosion in clay media under water-saturated conditions at 90° C: characterization of the corrosion interface

ML Schlegel, C Bataillon, C Blanc… - … Science & Technology, 2010 - ACS Publications
To understand the process governing iron corrosion in clay over centuries, the chemical and
mineralogical properties of solids formed by free or anodically activated corrosion of iron in …

Hydrogen uptake and diffusion in Callovo-Oxfordian clay rock for nuclear waste disposal technology

F Bardelli, C Mondelli, M Didier, JG Vitillo… - Applied …, 2014 - Elsevier
Abstract The Callovo-Oxfordian clay-rich rock formation is currently considered as host rock
barrier in the French geological repository facility for radioactive waste (Meuse/Haute …