Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics

A Mandal, MAD Taylor, BM Weight… - Chemical …, 2023 - ACS Publications
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …

Molecular polaritons for chemistry, photonics and quantum technologies

B **er, D Sidler, M Ruggenthaler… - The Journal of …, 2023 - ACS Publications
Experimental studies indicate that optical cavities can affect chemical reactions through
either vibrational or electronic strong coupling and the quantized cavity modes. However …

Control of photoswitching kinetics with strong light–matter coupling in a cavity

H Zeng, JB Pérez-Sánchez, CT Eckdahl… - Journal of the …, 2023 - ACS Publications
Most photochemistry occurs in the regime of weak light–matter coupling, in which a
molecule absorbs a photon and then performs photochemistry from its excited state. In the …

Unraveling a cavity-induced molecular polarization mechanism from collective vibrational strong coupling

D Sidler, T Schnap**er, A Obzhirov… - The Journal of …, 2024 - ACS Publications
We demonstrate that collective vibrational strong coupling of molecules in thermal
equilibrium can give rise to significant local electronic polarizations in the thermodynamic …

Consequences of vibrational strong coupling on supramolecular polymerization of porphyrins

K Joseph, B de Waal, SAH Jansen… - Journal of the …, 2024 - ACS Publications
Supramolecular polymers display interesting optoelectronic properties and, thus, deploy
multiple applications based on their molecular arrangement. However, controlling …

Non‐Polaritonic Effects in Cavity‐Modified Photochemistry

PA Thomas, WJ Tan, VG Kravets… - Advanced …, 2024 - Wiley Online Library
Strong coupling of molecules to vacuum fields is widely reported to lead to modified
chemical properties such as reaction rates. However, some recent attempts to reproduce …

Controlling molecular photoisomerization in photonic cavities through polariton funneling

I Lee, SR Melton, D Xu, M Delor - Journal of the American …, 2024 - ACS Publications
Strong coupling between photonic modes and molecular electronic excitations, creating
hybrid light-matter states called polaritons, is an attractive avenue for controlling chemical …

Resonance theory of vibrational strong coupling enhanced polariton chemistry and the role of photonic mode lifetime

W Ying, P Huo - Communications Materials, 2024 - nature.com
Recent experiments demonstrate polaritons under the vibrational strong coupling (VSC)
regime can modify chemical reactivity. Here, we present a complete theory of VSC-modified …