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Theoretical advances in polariton chemistry and molecular cavity quantum electrodynamics
When molecules are coupled to an optical cavity, new light–matter hybrid states, so-called
polaritons, are formed due to quantum light–matter interactions. With the experimental …
polaritons, are formed due to quantum light–matter interactions. With the experimental …
Molecular polaritons for chemistry, photonics and quantum technologies
Experimental studies indicate that optical cavities can affect chemical reactions through
either vibrational or electronic strong coupling and the quantized cavity modes. However …
either vibrational or electronic strong coupling and the quantized cavity modes. However …
Control of photoswitching kinetics with strong light–matter coupling in a cavity
Most photochemistry occurs in the regime of weak light–matter coupling, in which a
molecule absorbs a photon and then performs photochemistry from its excited state. In the …
molecule absorbs a photon and then performs photochemistry from its excited state. In the …
Unraveling a cavity-induced molecular polarization mechanism from collective vibrational strong coupling
We demonstrate that collective vibrational strong coupling of molecules in thermal
equilibrium can give rise to significant local electronic polarizations in the thermodynamic …
equilibrium can give rise to significant local electronic polarizations in the thermodynamic …
Consequences of vibrational strong coupling on supramolecular polymerization of porphyrins
Supramolecular polymers display interesting optoelectronic properties and, thus, deploy
multiple applications based on their molecular arrangement. However, controlling …
multiple applications based on their molecular arrangement. However, controlling …
Non‐Polaritonic Effects in Cavity‐Modified Photochemistry
Strong coupling of molecules to vacuum fields is widely reported to lead to modified
chemical properties such as reaction rates. However, some recent attempts to reproduce …
chemical properties such as reaction rates. However, some recent attempts to reproduce …
Controlling molecular photoisomerization in photonic cavities through polariton funneling
Strong coupling between photonic modes and molecular electronic excitations, creating
hybrid light-matter states called polaritons, is an attractive avenue for controlling chemical …
hybrid light-matter states called polaritons, is an attractive avenue for controlling chemical …
Resonance theory of vibrational strong coupling enhanced polariton chemistry and the role of photonic mode lifetime
Recent experiments demonstrate polaritons under the vibrational strong coupling (VSC)
regime can modify chemical reactivity. Here, we present a complete theory of VSC-modified …
regime can modify chemical reactivity. Here, we present a complete theory of VSC-modified …