Industrial ammonia production mainly relies on the conventional Haber–Bosch process
accompanied by high energy consumption and plentiful carbon dioxide emissions, which …

Activation of dinitrogen plays an important role in daily anthropogenic life, and the processes
by which this fixation occurs have been a longstanding and significant research focus within …

NH 3 production is dependent on the century-old Haber-Bosch process, which is energy and
capital intensive and relies on H 2 from steam reforming, hence, contributing to greenhouse …

Transition metal-driven small molecule activation is essential for the production of fuels and
chemicals or energy supply. The use of multimetallic catalysts, where two or more metal …

Herein we present a new viologen‐based radical‐containing metal–organic framework
(RMOF) Gd‐IHEP‐7, which upon heating in air undergoes a single‐crystal‐to‐single‐crystal …

Cluster complexes have attracted interest for decades due to their promise of drawing
analogies to metallic surfaces and metalloenzyme active sites, but only recently have …

Using a new hexanucleating anildophosphine ligand t BuLH3 (1, 3, 5-C6H9 (NHC6H3–5-F–
2-P (t Bu) 2) 3), the all-monovalent [FeI3] compound (t BuL) Fe3 (1) was isolated and …

Solar‐driven photocatalytic nitrogen fixation is a low‐energy and environmentally friendly
strategy for NH3 synthesis, which is considered as a possible alternative to the Haber …

The growth of multimetallic clusters and complexes can proceed in the presence of suitable
ligands, but often leads to polydisperse structures with poor solubility. As an alternative …

Conspectus Bimetallic motifs are a structural feature common to some of the most effective
and synthetically useful catalysts known, including in the active sites of many …