Designing sites in heterogeneous catalysis: are we reaching selectivities competitive with those of homogeneous catalysts?

F Zaera - Chemical Reviews, 2022 - ACS Publications
A critical review of different prominent nanotechnologies adapted to catalysis is provided,
with focus on how they contribute to the improvement of selectivity in heterogeneous …

Strategies and mechanisms of metal–ligand cooperativity in first-row transition metal complex catalysts

MR Elsby, RT Baker - Chemical Society Reviews, 2020 - pubs.rsc.org
The use of metal–ligand cooperation (MLC) by transition metal bifunctional catalysts has
emerged at the forefront of homogeneous catalysis science. Specially designed ligands can …

First-row transition metal (de) hydrogenation catalysis based on functional pincer ligands

L Alig, M Fritz, S Schneider - Chemical reviews, 2018 - ACS Publications
The use of 3d metals in de/hydrogenation catalysis has emerged as a competitive field with
respect to “traditional” precious metal catalyzed transformations. The introduction of …

Metal-catalyzed Markovnikov-type selective hydrofunctionalization of terminal alkynes

J Chen, WT Wei, Z Li, Z Lu - Chemical Society Reviews, 2024 - pubs.rsc.org
Metal-catalyzed highly Markovnikov-type selective hydrofunctionalization of terminal alkynes
provides a straightforward and atom-economical route to access 1, 1-disubstituted alkenes …

Homogeneous catalysis by cobalt and manganese pincer complexes

A Mukherjee, D Milstein - ACS Catalysis, 2018 - ACS Publications
Homogeneous catalysis of organic transformations by metal complexes has been mostly
based on complexes of noble metals. In recent years, tremendous progress has been made …

Homogeneous manganese-catalyzed hydrogenation and dehydrogenation reactions

Y Wang, M Wang, Y Li, Q Liu - Chem, 2021 - cell.com
The development of novel and efficient earth-abundant metal catalysts as inexpensive and
sustainable alternatives to noble-metal catalysts is a rapidly expanding and evolving field of …

Regulating electron transfer over asymmetric low-spin Co (II) for highly selective electrocatalysis

KH Wu, Y Liu, X Tan, Y Liu, Y Lin, X Huang, Y Ding… - Chem Catalysis, 2022 - cell.com
Modulating the steric-electronic configuration of metal-organic centers is key for tuning the
activity and selectivity of heterogeneous reactions, especially multi-electron transfer …

Recent progress in transition metal complexes supported by multidentate ligands featuring group 13 and 14 elements as coordinating atoms

T Komuro, Y Nakajima, J Takaya… - Coordination Chemistry …, 2022 - Elsevier
Over the past decade, significant progress has been made in the chemistry of transition
metal complexes supported by multidentate chelate ligands, such as pincer-type ligands, in …

Recent progress with pincer transition metal catalysts for sustainability

L Piccirilli, D Lobo Justo Pinheiro, M Nielsen - Catalysts, 2020 - mdpi.com
Our planet urgently needs sustainable solutions to alleviate the anthropogenic global
warming and climate change. Homogeneous catalysis has the potential to play a …

Recent developments in the chemistry of non-trigonal pnictogen pincer compounds: from bonding to catalysis

J Abbenseth, JM Goicoechea - Chemical Science, 2020 - pubs.rsc.org
The combination of well-established meridionally coordinating, tridentate pincer ligands with
group 15 elements affords geometrically constrained non-trigonal pnictogen pincer …