Linear block copolymer synthesis

H Dau, GR Jones, E Tsogtgerel, D Nguyen… - Chemical …, 2022 - ACS Publications
Block copolymers form the basis of the most ubiquitous materials such as thermoplastic
elastomers, bridge interphases in polymer blends, and are fundamental for the development …

Alkyl borane-mediated metal-free ring-opening (co) polymerizations of oxygenated monomers

C Zhang, X Geng, X Zhang, Y Gnanou… - Progress in Polymer …, 2023 - Elsevier
Sensibility to environmental concerns and the actual demand for polymeric materials free of
any metal contaminants in most applications have directed research towards significant …

Synthetic biodegradable polyhydroxyalkanoates (PHAs): Recent advances and future challenges

AH Westlie, EC Quinn, CR Parker, EYX Chen - Progress in Polymer …, 2022 - Elsevier
This article reviews the advances made over the past five decades of research in develo**
effective chemocatalytic pathways to synthesize polyhydroxyalkanoates (PHAs), a prominent …

Chemically recyclable polymer materials: polymerization and depolymerization cycles

G Xu, Q Wang - Green Chemistry, 2022 - pubs.rsc.org
The design and synthesis of chemically recyclable polymers, which can be reutilized as their
starting monomers or new value-added chemicals, has provided a practical approach to …

Advances in the use of CO 2 as a renewable feedstock for the synthesis of polymers

B Grignard, S Gennen, C Jérôme, AW Kleij… - Chemical Society …, 2019 - pubs.rsc.org
Carbon dioxide offers an accessible, cheap and renewable carbon feedstock for synthesis.
Current interest in the area of carbon dioxide valorisation aims at new, emerging …

N-Heterocyclic Carbenes in Materials Chemistry

CA Smith, MR Narouz, PA Lummis, I Singh… - Chemical …, 2019 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …

Catalysis as an enabling science for sustainable polymers

X Zhang, M Fevre, GO Jones, RM Waymouth - Chemical reviews, 2018 - ACS Publications
The replacement of current petroleum-based plastics with sustainable alternatives is a
crucial but formidable challenge for the modern society. Catalysis presents an enabling tool …

Polyethylene terephthalate degradation under natural and accelerated weathering conditions

T Sang, CJ Wallis, G Hill, GJP Britovsek - European polymer journal, 2020 - Elsevier
This review presents an overview of the state of the art in understanding of the chemistries
behind polyethylene terephthalate (PET) degradation under hydrolytic and photolytic …

Towards high-performance sustainable polymers via isomerization-driven irreversible ring-opening polymerization of five-membered thionolactones

P Yuan, Y Sun, X Xu, Y Luo, M Hong - Nature Chemistry, 2022 - nature.com
The development of sustainable polymers that possess useful material properties
competitive with existing petroleum-derived polymers is a crucial goal but remains a …

50th Anniversary Perspective: There Is a Great Future in Sustainable Polymers

DK Schneiderman, MA Hillmyer - Macromolecules, 2017 - ACS Publications
It is likely that a half-century ago even enthusiastic and optimistic proponents of the synthetic
polymer industry (Mr. McGuire included) could not have predicted the massive scale on …