Shape-persistent purely organic molecular architectures have attracted tremendous
research interest in the past few decades. Dynamic Covalent Chemistry (DCvC), which …

Expanded helicenes are an emerging class of helical nanocarbons composed of alternating
linear and angularly fused rings, which give rise to an internal cavity and a large diameter …

Arynes due to their transient nature leads to remarkable and versatile applications in the
synthetic world. Apparently, researchers have focused on the construction of simple to …

For numerous enabling features and strategic virtues, contemporary alkyne metathesis is
increasingly recognized as a formidable synthetic tool. Central to this development was the …

Molybdenum alkylidynes endowed with tripodal silanolate ligands belong to the most active
and selective catalysts for alkyne metathesis known to date. This paper describes a new …

Carbon nanobelts are molecules of high fundamental and technological interest due to their
structural similarity to carbon nanotubes, of which they are molecular cutouts. Despite this …

The rapid and precise creation of complex molecules while controlling multiple selectivities
is the principal objective in synthetic chemistry. Combining data science and organic …

Expanded helicenes are large, structurally flexible π-frameworks that can be viewed as
building blocks for more complex chiral nanocarbons. Here we report a gram-scale …

Recently reported reactions of group 4 metallocene bis (trimethylsilyl) acetylene complexes
from the last two years are summarized. This could be considered as a never-ending story. A …

Triarylsilanolates are privileged ancillary ligands for molybdenum alkylidyne catalysts for
alkyne metathesis but lead to disappointing results and poor stability in the tungsten series …