Hydrogen-bonded framework of a cobalt (II) complex showing superior stability and field-induced slow magnetic relaxation

D Shao, P Peng, M You, LF Shen, SY She… - Inorganic …, 2022 - ACS Publications
A unique hydrogen-bonded organic–inorganic framework (HOIF) constructed from a
mononuclear cobalt (II) complex,[Co (MCA) 2·(H2O) 2](HMCA= 4-imidazolecarboxylic acid) …

Incorporating highly anisotropic four-coordinate Co (II) ions within one-dimensional coordination chains

T Long, J Yang, S Moorthy, D Shao… - Crystal Growth & …, 2023 - ACS Publications
Low-coordinate metallic ions have been well recognized for constructing good-performance
single ion magnets (SIMs) due to their enhanced magnetic anisotropy; however, the …

Supramolecular encapsulation of hexaaquacobalt (II) cations in a hydrogen-bonded framework for slow magnetic relaxation and high proton conduction

D Shao, Y Zhou, X Yang, J Yue, S Ming, XQ Wei… - Dalton …, 2022 - pubs.rsc.org
The supramolecular assembly of hexaaquacobalt (II) nitrate and a tetradentate carboxylate
ligand resulted in the isolation of a cobalt hydrogen-bonded organic framework (HOF) …

Metalo Hydrogen-Bonded Organic Frameworks Constructed by Coordinated Chains for Magnetic and Proton-Conductive Bifunctionality

J Dong, L Huang, L Shi, J Yang, Y Wan… - Inorganic …, 2024 - ACS Publications
Metalo hydrogen-bonded organic frameworks (MHOFs) have received growing interest in
designing crystalline functional materials. However, reports on bifunctional MHOFs showing …

Magnetic and Porous Regulation in Cobalt (II) Hydrogen-Bonded Organic Framework via Supramolecular Isomerism

JY Zhu, K Kumari, SJ Chen, D Shao, J Yang… - Crystal Growth & …, 2024 - ACS Publications
Supramolecular isomerism has been recognized as an effective strategy for manipulating
structures and properties, particularly in metal–hydrogen-bonded organic frameworks …

A porous cobalt (II)–organic framework exhibiting high room temperature proton conductivity and field-induced slow magnetic relaxation

Y Zhou, S Moorthy, XQ Wei, SK Singh, Z Tian… - Dalton …, 2023 - pubs.rsc.org
A two-dimensional (2D) cobalt (II) metal–organic framework (MOF) constructed by a ditopic
organic ligand, formulated as {[Co (Hbic)(H2O)]· 4H2O} n (1)(H2bic= 1H-benzimidazole-5 …

Binuclear cobalt (II) and two-dimensional manganese (II) coordination compounds self-assembled by mixed bipyridine-tetracarboxylic ligands with single-ion magnet …

DQ Wu, K Kumari, Y Wan, X Gao, M Guo, G Liu… - Dalton …, 2023 - pubs.rsc.org
A cobalt (II) complex and manganese (II) coordination polymer, formulated as [Co2
(H2btca)(mbpy) 4][H2btca]· 4H2O (1) and {Mn2 (btca)(mbpy) 2 (H2O) 2} n (2)(H4btca= 1, 2 …

Field-induced slow magnetic relaxation behaviours in binuclear cobalt (ii) metallocycles and exchange-coupled clusters

D Shao, S Moorthy, Y Zhou, ST Wu, JY Zhu… - Dalton …, 2022 - pubs.rsc.org
Precise control of the structures and magnetic properties of a molecular material constitutes
an important challenge to realize tailor-made magnetic function. Herein, we report that the …

Tuning chain topologies and magnetic anisotropy in one-dimensional cobalt (II) coordination polymers via distinct dicarboxylates

Z Tian, S Moorthy, H **ang, P Peng, M You, Q Zhang… - …, 2022 - pubs.rsc.org
Based on a terpyridine derivative and two different dicarboxylate ligands, two new cobalt (II)
coordination polymers, namely [Co (pytpy)(DClbdc)] n (1) and [Co (pytpy)(ndc)] n (2)(pytpy …

Cobalt (II) coordination polymers with single-ion magnet property

Y Wan, YL Zhang, Q Zhang, SY Yang, D Shao - CrystEngComm, 2024 - pubs.rsc.org
Single-ion magnets (SIMs) are composed of 3d and/or 4f complexes with substantial energy
barriers that inhibit spin reversal at the molecular level. The magnetic bistability of SIMs …