[HTML][HTML] Radical-promoted single-unit monomer insertion (SUMI)[aka. reversible-deactivation radical addition (RDRA)]

C Boyer, M Kamigaito, K Satoh, G Moad - Progress in Polymer Science, 2023 - Elsevier
We survey progress in the development of the processes for radical-promoted single-unit
monomer insertion (SUMI) or reversible deactivation radical addition (RDRA), focussing on …

Chromatographic Separation: A Versatile Strategy to Prepare Discrete and Well-Defined Polymer Libraries

EA Murphy, C Zhang, CM Bates… - Accounts of Chemical …, 2024 - ACS Publications
Conspectus The preparation of discrete and well-defined polymers is an emerging strategy
for emulating the remarkable precision achieved by macromolecular synthesis in nature …

Efficient creation and morphological analysis of ABC triblock terpolymer libraries

EA Murphy, YQ Chen, K Albanese… - …, 2022 - ACS Publications
Multiblock copolymers with increasingly complex block sequences─ for example, triblock
terpolymers─ offer unique opportunities to create nanostructured materials, but this …

Accelerated discovery and map** of block copolymer phase diagrams

EA Murphy, SJ Skala, D Kottage, PA Kohl, Y Li… - Physical Review …, 2024 - APS
Block copolymers are widely used in many applications due to their spontaneous self-
assembly into a variety of nanoscale morphologies. However, a grand challenge in …

PET-RAFT single unit monomer insertion of β-methylstyrene derivatives: RAFT degradation and reaction selectivity

L Zhang, R Liu, S Lin, J Xu - Chemical Communications, 2021 - pubs.rsc.org
Reversible addition–fragmentation chain transfer (RAFT) single unit monomer insertion
(SUMI) of β-methylstyrene derivatives into diverse RAFT agents presented fast reaction …

Reading mixtures of uniform sequence-defined macromolecules to increase data storage capacity

M Frölich, D Hofheinz, MAR Meier - Communications chemistry, 2020 - nature.com
In recent years, the field of molecular data storage has emerged from a niche to a vibrant
research topic. Herein, we describe a simultaneous and automated read-out of data stored …

Bioinspired and biomimetic nucleobase-containing polymers: the effect of selective multiple hydrogen bonds

N Yao, J Wu, G Liu, Z Hua - Chemical Science, 2024 - pubs.rsc.org
Bioinspired and biomimetic nucleobase-containing polymers are a series of polydisperse
nucleic acid analogs, mainly obtaining through highly efficient and scalable step-growth or …

Synthesis of nucleobase functionalised block copolymers towards precision self-assembly

I Abeysekera, L Maes, T Junkers - Polymer Chemistry, 2024 - pubs.rsc.org
The formation of nanoaggregates from continuous flow assembly of nucleobase-
functionalized amphiphilic block co-polymers is investigated. Block copolymers (BCPs) …

Chain stretching in brushes favors sequence recognition for nucleobase-functionalized flexible precise oligomers

K Grafskaia, Q Qin, J Li, D Magnin, D Dellemme… - Soft Matter, 2024 - pubs.rsc.org
Six different flexible stereocontrolled oligo (triazole-urethane) s substituted by precise
sequences of nucleobases or analogs are synthesized. Molecular dynamics simulations …

Guanine and cytosine‐containing acrylic supramolecular networks

B Liu, GA Spiering, RK McDonough… - Journal of Polymer …, 2024 - Wiley Online Library
This manuscript describes the synthesis and characterization of guanine and cytosine‐
containing supramolecular copolymers, which are inspired from the guanine and cytosine …