Distinctive features and challenges in catenane chemistry

HY Au-Yeung, Y Deng - Chemical Science, 2022 - pubs.rsc.org
From being an aesthetic molecular object to a building block for the construction of
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …

Direct synthetic routes to functionalised crown ethers

F Nicoli, M Baroncini, S Silvi, J Groppi… - Organic Chemistry …, 2021 - pubs.rsc.org
Crown ethers are macrocyclic hosts that can complex a wide range of inorganic and organic
cations as well as neutral guest species. Their widespread utilization in several areas of …

Unimolecular chiral step** inversion machine

Y Sun, L Liu, L Jiang, Y Chen, H Zhang… - Journal of the …, 2023 - ACS Publications
Intelligent molecular machines that are driven by light, electricity, and temperature have
attracted considerable interest in the fields of chemistry, materials, and biology. Herein, a …

Persistent Radical Tetrathiafulvalene‐Based 2D Metal‐Organic Frameworks and Their Application in Efficient Photothermal Conversion

J Su, N Xu, R Murase, ZM Yang… - Angewandte …, 2021 - Wiley Online Library
A series of stable radical 2D metal‐organic frameworks has been assembled.(m‐TTFTB) 3
(m‐Tetrathiafulvalene‐tetrabenzoate) trimer building blocks are beneficial for the stability of …

Construction of covalent organic frameworks with crown ether struts

S An, Q Xu, Z Ni, J Hu, C Peng, L Zhai… - Angewandte Chemie …, 2021 - Wiley Online Library
Crown ethers are a class of macrocyclic molecules with unique flexible structures but they
are rarely integrated in covalent organic frameworks (COFs). To date, employing flexible …

Compact rotaxane superbases

MJ Power, DTJ Morris… - Journal of the …, 2023 - ACS Publications
Challenges for the development of efficacious new superbases include their ease of
synthesis, chemical stability, and high basicity, while minimizing nucleophilicity is important …

Recent advances in higher order rotaxane architectures

HY Zhou, QS Zong, Y Han, CF Chen - Chemical Communications, 2020 - pubs.rsc.org
Despite dramatic advances in the template-directed synthesis of archetypal [2] rotaxanes,
higher order rotaxanes with multiple molecular components (rings or dumbbells) are …

Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes

A Saura-Sanmartin, CA Schalley - Chem, 2023 - cell.com
Rotaxanes, pseudorotaxanes, and catenanes have attracted the interest of many
researchers because of the special features provided by the mechanical bond. The selective …

pH-Controlled motions in mechanically interlocked molecules

HY Zhou, Y Han, CF Chen - Materials Chemistry Frontiers, 2020 - pubs.rsc.org
Mechanically interlocked molecules (MIMs), especially rotaxanes and catenanes, allow
large-amplitude movement at the molecular level, making them the perfect prototypes for …

Enhancing the photothermal conversion of tetrathiafulvalene-based MOFs by redox do** and plasmon resonance

J Su, P Cai, T Yan, ZM Yang, S Yuan, JL Zuo… - Chemical …, 2022 - pubs.rsc.org
Near-infrared (NIR) photothermal materials hold great promise for use in several
applications, particularly in photothermal therapy, diagnosis, and imaging. However, current …