Distinctive features and challenges in catenane chemistry
From being an aesthetic molecular object to a building block for the construction of
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …
molecular machines, catenanes and related mechanically interlocked molecules (MIMs) …
Direct synthetic routes to functionalised crown ethers
Crown ethers are macrocyclic hosts that can complex a wide range of inorganic and organic
cations as well as neutral guest species. Their widespread utilization in several areas of …
cations as well as neutral guest species. Their widespread utilization in several areas of …
Unimolecular chiral step** inversion machine
Y Sun, L Liu, L Jiang, Y Chen, H Zhang… - Journal of the …, 2023 - ACS Publications
Intelligent molecular machines that are driven by light, electricity, and temperature have
attracted considerable interest in the fields of chemistry, materials, and biology. Herein, a …
attracted considerable interest in the fields of chemistry, materials, and biology. Herein, a …
Persistent Radical Tetrathiafulvalene‐Based 2D Metal‐Organic Frameworks and Their Application in Efficient Photothermal Conversion
A series of stable radical 2D metal‐organic frameworks has been assembled.(m‐TTFTB) 3
(m‐Tetrathiafulvalene‐tetrabenzoate) trimer building blocks are beneficial for the stability of …
(m‐Tetrathiafulvalene‐tetrabenzoate) trimer building blocks are beneficial for the stability of …
Construction of covalent organic frameworks with crown ether struts
S An, Q Xu, Z Ni, J Hu, C Peng, L Zhai… - Angewandte Chemie …, 2021 - Wiley Online Library
Crown ethers are a class of macrocyclic molecules with unique flexible structures but they
are rarely integrated in covalent organic frameworks (COFs). To date, employing flexible …
are rarely integrated in covalent organic frameworks (COFs). To date, employing flexible …
Compact rotaxane superbases
MJ Power, DTJ Morris… - Journal of the …, 2023 - ACS Publications
Challenges for the development of efficacious new superbases include their ease of
synthesis, chemical stability, and high basicity, while minimizing nucleophilicity is important …
synthesis, chemical stability, and high basicity, while minimizing nucleophilicity is important …
Recent advances in higher order rotaxane architectures
HY Zhou, QS Zong, Y Han, CF Chen - Chemical Communications, 2020 - pubs.rsc.org
Despite dramatic advances in the template-directed synthesis of archetypal [2] rotaxanes,
higher order rotaxanes with multiple molecular components (rings or dumbbells) are …
higher order rotaxanes with multiple molecular components (rings or dumbbells) are …
Self-sorting as a versatile strategy in the synthesis of rotaxanes and catenanes
Rotaxanes, pseudorotaxanes, and catenanes have attracted the interest of many
researchers because of the special features provided by the mechanical bond. The selective …
researchers because of the special features provided by the mechanical bond. The selective …
pH-Controlled motions in mechanically interlocked molecules
HY Zhou, Y Han, CF Chen - Materials Chemistry Frontiers, 2020 - pubs.rsc.org
Mechanically interlocked molecules (MIMs), especially rotaxanes and catenanes, allow
large-amplitude movement at the molecular level, making them the perfect prototypes for …
large-amplitude movement at the molecular level, making them the perfect prototypes for …
Enhancing the photothermal conversion of tetrathiafulvalene-based MOFs by redox do** and plasmon resonance
Near-infrared (NIR) photothermal materials hold great promise for use in several
applications, particularly in photothermal therapy, diagnosis, and imaging. However, current …
applications, particularly in photothermal therapy, diagnosis, and imaging. However, current …