Structure of deep eutectic solvents (DESs): What we know, what we want to know, and why we need to know it

NM Stephens, EA Smith - Langmuir, 2022 - ACS Publications
Deep eutectic solvents (DESs) are a tunable class of solvents with many advantageous
properties including good thermal stability, facile synthesis, low vapor pressure, and low-to …

Atomistic modelling approaches to understanding the interfaces of ionic liquid electrolytes for batteries and electrochemical devices

F Chen - Current Opinion in Electrochemistry, 2022 - Elsevier
Interface stability is a core issue in battery research. However, interfacial problems are the
most complex dilemma to solve, and molecular modelling becomes increasingly …

Polar organic cations at electrified metal with superconcentrated ionic liquid electrolyte and implications for sodium metal batteries

DA Rakov, J Sun, SA Ferdousi, PC Howlett… - ACS Materials …, 2022 - ACS Publications
Understanding the potential-induced changes across the electrode/electrolyte interface, the
so-called electric double layer (EDL), is essential to adjust the working properties of energy …

In Situ Measurement of Effective Gate Bias Voltage in Ionic Liquid-Gated Organic Field-Effect Transistors: Exploring Intrinsic Performance and Trap Density of States

Y Yadav, SP Singh - ACS Applied Materials & Interfaces, 2023 - ACS Publications
Electric double layer (EDL)-mediated transistors with ionic liquid (IL) gating have garnered
substantial interest due to their exceptional properties, such as high transconductance and …

Theoretical Insight into the Imidazolium-Based Ionic Liquid Interface Structure and Differential Capacitance on Au (111): Effects of the Cationic Substituent Group

Y Wang, G Tian - Langmuir, 2023 - ACS Publications
Electric double layers (EDLs) play a key role in the electrochemical and energy storage of
supercapacitors. It is important to understand the structure and properties of EDLs. In this …

Influence of surface nanostructure-induced innermost ion structuring on capacitance of carbon/ionic liquid double layers

YJ Tu, ST Peng - Physical Chemistry Chemical Physics, 2024 - pubs.rsc.org
Ionic liquids have drawn great interest as electrolytes for energy storage applications in
which they form characteristic electrical double layers at electrode interfaces. For ionic …

Importance of anion–anion pairing for capacitance of carbon/ionic liquid interfaces

YJ Tu, SC Wu, JG McDaniel - The Journal of Physical Chemistry C, 2022 - ACS Publications
The capacitance of carbon electrodes can be enhanced by tuning nanoscale roughness of
the electrode surface, which facilitates separation between cations and anions within the …

Water and ions in electrified silica nano-pores: a molecular dynamics study

M Tavakol, K Voïtchovsky - Physical Chemistry Chemical Physics, 2024 - pubs.rsc.org
Solid–liquid interfaces (SLIs) are ubiquitous in science and technology from the
development of energy storage devices to the chemical reactions occurring in the biological …

Rheological Characteristics of Ionic Liquids under Nanoconfinement

M Han, SA Rogers, RM Espinosa-Marzal - Langmuir, 2022 - ACS Publications
While the dynamic properties of ionic liquids (ILs) in nanoconfinement play a crucial role in
the performance of IL-based electrochemical and mechanical devices, experimental work …

Exploring the Conformational Space of a Sulfonyl-Based Ionic Liquid on Platinum-Based Mono and Bimetallic Surfaces

AP Sarkar, R Sahu, S Giri, A Anoop, SK Reddy - Langmuir, 2025 - ACS Publications
Understanding the arrangement of ionic liquids at the interface and their interactions with the
surface is crucial for enhancing selectivity in heterogeneous reactions for practical …