Two-dimensional spectroscopy at terahertz frequencies

J Lu, X Li, Y Zhang, HY Hwang, BK Ofori-Okai… - Multidimensional Time …, 2019 - Springer
Multidimensional spectroscopy in the visible and infrared spectral ranges has become a
powerful technique to retrieve dynamic correlations and couplings in wide-ranging systems …

Ultra-broadband EPR spectroscopy in field and frequency domains

P Neugebauer, D Bloos, R Marx, P Lutz… - Physical Chemistry …, 2018 - pubs.rsc.org
Electron paramagnetic resonance (EPR) is a powerful technique to investigate the electronic
and magnetic properties of a wide range of materials. We present the first combined …

Applying Unconventional Spectroscopies to the Single‐Molecule Magnets, Co(PPh3)2X2 (X=Cl, Br, I): Unveiling Magnetic Transitions and Spin‐Phonon Coupling

AN Bone, CN Widener, DH Moseley… - … A European Journal, 2021 - Wiley Online Library
Large separation of magnetic levels and slow relaxation in metal complexes are desirable
properties of single‐molecule magnets (SMMs). Spin‐phonon coupling (interactions of …

A trigonal prismatic cobalt (II) complex as a single molecule magnet with a reduced contribution from quantum tunneling

AA Pavlov, DY Aleshin, SA Savkina, AS Belov… - …, 2019 - Wiley Online Library
Herein, we report a new trigonal prismatic cobalt (II) complex that behaves as a single
molecule magnet. The obtained zero‐field splitting, which is also directly accessed by THz …

Probing the Magnetic Anisotropy of Co (II) Complexes Featuring Redox-Active Ligands

P Kumar, DJ SantaLucia… - Inorganic …, 2020 - ACS Publications
Coordination complexes that possess large magnetic anisotropy (otherwise known as zero-
field splitting, ZFS) have possible applications in the field of magnetic materials, including …

Slow Magnetic Relaxation in Intermediate Spin S = 3/2 Mononuclear Fe(III) Complexes

X Feng, SJ Hwang, JL Liu, YC Chen… - Journal of the …, 2017 - ACS Publications
Magneto-structural correlation studies of mononuclear intermediate S= 3/2 Fe (III)
complexes,(PMe3) 2FeCl3 (1) and (PMe2Ph) 2FeCl3 (2), demonstrate the influence of local …

Advanced Spectroscopic and Computational Studies of a Cobalt (II) Coordination Polymer with Single-Ion-Magnet Properties

P Tin, AN Bone, NN Bui, YQ Zhang… - The Journal of …, 2022 - ACS Publications
Two-dimensional (2D) coordination polymer (CP)[CoIII (CN) 6] 2 [CoII (TODA)] 3· 7H2O
(TODA= 1, 4, 10-trioxa-7, 13-diazacyclopentadecane, Co-TODA) was reported earlier to …

Tracking nuclear motion in single-molecule magnets using femtosecond X-ray absorption spectroscopy

K Barlow, R Phelps, J Eng, T Katayama… - Nature …, 2024 - nature.com
The development of new data storage solutions is crucial for emerging digital technologies.
Recently, all-optical magnetic switching has been achieved in dielectrics, proving to be …

A new series of tetrahedral Co (ii) complexes [CoLX 2](X= NCS, Cl, Br, I) manifesting single-ion magnet features

AK Mondal, M Sundararajan, S Konar - Dalton Transactions, 2018 - pubs.rsc.org
A series of tetrahedral CoII complexes [CoLX2](X= NCS (1), Cl (2), Br (3) and I (4); L= 9, 9-
dimethyl-4, 5-bis (diphenylphosphino) xanthene) based on a P-donor ligand has been …

Limitations on the D-Parameter in Ni(II) Complexes

J Titiš, C Rajnák, R Boča - The Journal of Physical Chemistry …, 2023 - ACS Publications
A number of hexacoordinate, pentacoordinate, and tetracoordinate Ni (II) complexes have
been investigated by applying ab initio CASSCF+ NEVPT2+ SOC calculations and …