Targeting of high-valent iron-TAML activators at hydrocarbons and beyond
TJ Collins, AD Ryabov - Chemical reviews, 2017 - ACS Publications
TAML activators of peroxides are iron (III) complexes. The ligation by four deprotonated
amide nitrogens in macrocyclic motifs is the signature of TAMLs where the macrocyclic …
amide nitrogens in macrocyclic motifs is the signature of TAMLs where the macrocyclic …
Metal-catalyzed asymmetric sulfoxidation, epoxidation and hydroxylation by hydrogen peroxide
H Srour, P Le Maux, S Chevance… - Coordination Chemistry …, 2013 - Elsevier
The development of environmentally benign reactions is an important goal in synthetic
organic chemistry and chemical engineering. However, catalytic enantioselective oxidations …
organic chemistry and chemical engineering. However, catalytic enantioselective oxidations …
Metal ion effect on the switch of mechanism from direct oxygen transfer to metal ion-coupled electron transfer in the sulfoxidation of thioanisoles by a non-heme iron …
The mechanism of sulfoxidation of thioaniosoles by a non-heme iron (IV)− oxo complex is
switched from direct oxygen transfer to metal ion-coupled electron transfer by the presence …
switched from direct oxygen transfer to metal ion-coupled electron transfer by the presence …
Synthesis of sulfoxides by the hydrogen peroxide induced oxidation of sulfides catalyzed by iron tetrakis (pentafluorophenyl) porphyrin: Scope and chemoselectivity
E Baciocchi, MF Gerini, A Lapi - The Journal of Organic Chemistry, 2004 - ACS Publications
The oxidation of sulfides with H2O2 catalyzed by iron tetrakis (pentafluorophenyl) porphyrin
in EtOH is an efficient and chemoselective process. With a catalyst concentration 0.03 …
in EtOH is an efficient and chemoselective process. With a catalyst concentration 0.03 …
Scandium Ion-Enhanced Oxidative Dimerization and N-Demethylation of N,N-Dimethylanilines by a Non-Heme Iron(IV)-Oxo Complex
Oxidative dimerization of N, N-dimethylaniline (DMA) occurs with a nonheme iron (IV)-oxo
complex,[FeIV (O)(N4Py)] 2+(N4Py= N, N-bis (2-pyridylmethyl)-N-bis (2-pyridyl) …
complex,[FeIV (O)(N4Py)] 2+(N4Py= N, N-bis (2-pyridylmethyl)-N-bis (2-pyridyl) …
First enantioselective iron-porphyrin-catalyzed sulfide oxidation with aqueous hydrogen peroxide
P Le Maux, G Simonneaux - Chemical Communications, 2011 - pubs.rsc.org
First enantioselective iron- porphyrin -catalyzed sulfide oxidation with aqueous hydrogen
peroxide - Chemical Communications (RSC Publishing) DOI:10.1039/C1CC11675D Royal …
peroxide - Chemical Communications (RSC Publishing) DOI:10.1039/C1CC11675D Royal …
Coupled X-ray absorption/UV–vis monitoring of fast oxidation reactions involving a nonheme iron–oxo complex
Time-resolved X-ray absorption (XAS) and UV–vis spectroscopies with millisecond
resolution are used simultaneously to investigate oxidation reactions of organic substrates …
resolution are used simultaneously to investigate oxidation reactions of organic substrates …
Sulfoxidation Mechanisms Catalyzed by Cytochrome P450 and Horseradish Peroxidase Models: Spin Selection Induced by the Ligand,
The sulfoxidation of dimethyl sulfide (DMS), by two different heme-type enzyme models
(without the protein), namely, horseradish peroxidase (HRP) and cytochrome P450 (P450) …
(without the protein), namely, horseradish peroxidase (HRP) and cytochrome P450 (P450) …
Biomimetic metalloporphines and metalloporphyrins as potential tools for delignification: Molecular mechanisms and application perspectives
Lignin is a recalcitrant polymer arising from addition polymerization of phenylpropanoid
units via an oxidative, enzyme-catalyzed radical mechanism. Lignin removal is a serious …
units via an oxidative, enzyme-catalyzed radical mechanism. Lignin removal is a serious …
Selective oxidation of aromatic sulfide catalyzed by an artificial metalloenzyme: new activity of hemozymes
R Ricoux, M Allard, R Dubuc, C Dupont… - Organic & …, 2009 - pubs.rsc.org
Two new artificial hemoproteins or “hemozymes”, obtained by non covalent insertion of Fe
(III)-meso-tetra-p-carboxy-and-p-sulfonato-phenylporphyrin into xylanase A from …
(III)-meso-tetra-p-carboxy-and-p-sulfonato-phenylporphyrin into xylanase A from …