Dynamics of polymer segments, polymer chains, and nanoparticles in polymer nanocomposite melts: A review

EJ Bailey, KI Winey - Progress in Polymer Science, 2020 - Elsevier
The addition of nanoparticles (NPs) to a polymer matrix, forming a polymer nanocomposite
(PNC), is known to alter the microscopic dynamic processes of both species which leads to …

Irreversible adsorption of polymer melts and nanoconfinement effects

S Napolitano - Soft Matter, 2020 - pubs.rsc.org
For almost a decade, growing experimental evidence has revealed a strong correlation
between the properties of nanoconfined polymers and the number of chains irreversibly …

[HTML][HTML] Focus: Structure and dynamics of the interfacial layer in polymer nanocomposites with attractive interactions

S Cheng, B Carroll, V Bocharova, JM Carrillo… - The Journal of …, 2017 - pubs.aip.org
In recent years it has become clear that the interfacial layer formed around nanoparticles in
polymer nanocomposites (PNCs) is critical for controlling their macroscopic properties. The …

Particle tracking of nanoparticles in soft matter

KA Rose, M Molaei, MJ Boyle, D Lee… - Journal of Applied …, 2020 - pubs.aip.org
Recent advances in optical microscopy instrumentation and processing techniques have led
to imaging that both breaks the diffraction barrier and enables sub-pixel resolution. This …

Scaling perspective on dynamics of nanoparticles in polymers: length-and time-scale dependent nanoparticle–polymer coupling

T Ge - Macromolecules, 2023 - ACS Publications
The motion of nanoparticles in a polymer matrix is dictated by the intricate coupling of the
nanoparticles and surrounding polymers. Various length-and time-scale dependent features …

Collective nanoparticle dynamics associated with bridging network formation in model polymer nanocomposites

BM Yavitt, D Salatto, Y Zhou, Z Huang, M Endoh… - ACS …, 2021 - ACS Publications
The addition of nanoparticles (NPs) to polymers is a powerful method to improve the
mechanical and other properties of macromolecular materials. Such hybrid polymer–particle …

Nonuniversal Dynamics of Hyperbranched Metallo-Supramolecular Polymer Networks by the Spontaneous Formation of Nanoparticles

M Ahmadi, M Bauer, J Berg, S Seiffert - ACS nano, 2024 - ACS Publications
Various transient and permanent bonds are commonly combined in increasingly complex
hierarchical structures to achieve biomimetic functions, along with high mechanical …

Strong reduction in amplitude of the interfacial segmental dynamics in polymer nanocomposites

I Popov, B Carroll, V Bocharova, AC Genix… - …, 2020 - ACS Publications
Despite the wide use of polymer nanocomposites (PNCs) in various applications, our
understanding of the microscopic parameters controlling their macroscopic properties …

Structural and dynamical roles of bound polymer chains in rubber reinforcement

D Salatto, JMY Carrillo, MK Endoh, T Taniguchi… - …, 2021 - ACS Publications
The addition of nanofillers to rubber matrices is a powerful route to improve the mechanical
properties. Here, we focus on a molecular understanding of basic mechanisms that are …