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From unregulated networks to designed microstructures: introducing heterogeneity at different length scales in photopolymers for additive manufacturing
Photopolymers have been optimized as protective and decorative coating materials for
decades. However, with the rise of additive manufacturing technologies, vat …
decades. However, with the rise of additive manufacturing technologies, vat …
Phase separation of polymer mixtures driven by photochemical reactions: current status and perspectives
Q Tran‐Cong‐Miyata, H Nakanishi - Polymer International, 2017 - Wiley Online Library
Phase separation of polymer mixtures induced by photo‐crosslinking and
photopolymerization is summarized from the viewpoint of competing interactions in …
photopolymerization is summarized from the viewpoint of competing interactions in …
Kinetically controlled photoinduced phase separation for hybrid radical/cationic systems
Controlling phase separation in polymer systems has shown significant promise in
combining properties of different components into an integrated polymer system. In this …
combining properties of different components into an integrated polymer system. In this …
Patterning perovskite quantum dots using photopolymerization
M Morinaga, T Iwaki, H Tanaka, I Lagzi… - ACS Applied Materials …, 2023 - ACS Publications
All-inorganic cesium lead halide perovskite quantum dots (QDs) have several potential
applications, owing to their unique optical and electronic properties. However, patterning …
applications, owing to their unique optical and electronic properties. However, patterning …
Polymerization-induced vitrification and kinetic heterogenization at the onset of the Trommsdorff effect
Y Suzuki, Y Shinagawa, E Kato, R Mishima… - …, 2021 - ACS Publications
The reaction kinetics during bulk free radical polymerization is still not fully understood. As
the reaction proceeds, many parameters, including monomer/polymer fraction, radical …
the reaction proceeds, many parameters, including monomer/polymer fraction, radical …
Photopolymerization-induced phase separation kinetics explored by intermittent irradiation
In this work, we explore the kinetics of the photopolymerization-induced phase separation
(photo-PIPS) process and the interplay of mechanisms controlling the development of the …
(photo-PIPS) process and the interplay of mechanisms controlling the development of the …
Modification of linear prepolymers to tailor heterogeneous network formation through photo-initiated polymerization-induced phase separation
Polymerization-induced phase separation (PIPS) was studied in ambient
photopolymerizations of triethylene glycol dimethacrylate (TEGDMA) modified by poly …
photopolymerizations of triethylene glycol dimethacrylate (TEGDMA) modified by poly …
Thermoplastic elastomer obtained by photopolymerization‐induced concomitant macrophase and microphase separations
X Pascassio‐Comte, V Pellerin… - Journal of Polymer …, 2024 - Wiley Online Library
We report on concomitant photoinitiated polymerization‐induced macrophase and
microphase separation strategies to produce hierarchically structured recyclable poly (n …
microphase separation strategies to produce hierarchically structured recyclable poly (n …
Influences of wetting and shrinkage on the phase separation process of polymer mixtures induced by photopolymerization
N Kimura, K Kawazoe, H Nakanishi, T Norisuye… - Soft Matter, 2013 - pubs.rsc.org
Phase separation induced by photopolymerization was investigated for a mixture composed
of a polystyrene derivative and methyl methacrylate (MMA) monomer. The …
of a polystyrene derivative and methyl methacrylate (MMA) monomer. The …
Tricontinuous morphology of ternary polymer blends driven by photopolymerization: Reaction and phase separation kinetics
T Shukutani, T Myojo, H Nakanishi, T Norisuye… - …, 2014 - ACS Publications
Phase separation of a ternary mixture composed of poly (ethyl acrylate) and poly (ethyl
methacrylate) derivatives dissolved in methyl methacrylate monomer was induced and …
methacrylate) derivatives dissolved in methyl methacrylate monomer was induced and …