Metabolic and signaling biochemical pathways have numerous steps that involve the
hydrolytic cleavage of peptide or phosphate ester bonds. Although both types of bonds are …

Purple acid phosphatases (PAPs) contain a dinuclear metal center in their active site and
hydrolyze phosphoric acid esters at low pH. Characteristic of this group of acid …

Purple acid phosphatase is a widely distributed non-specific phosphomonoesterase. X-ray
structures of the dimeric 111-kDa Fe (III)-Zn (II) kidney bean purple acid phosphatase …

Mononuclear iron (II) α-keto carboxylate and carboxylate compounds of the sterically
hindered tridentate face-cap** ligand TpPh2 (TpPh2= hydrotris (3, 5-diphenylpyrazol-1-yl) …

The crystal structure of purple acid phosphatase from rat bone has been determined by
molecular replacement and the structure has been refined to 2.2 Å resolution to an R-factor …

New asymmetrical ligands (H2L) have been synthesized to provide both a bridging and a
terminal phenolate to a pair of iron ions in order to mimic the binding of a single terminal …

Glyoxalase 2 is a β-lactamase fold-containing enzyme that appears to be involved with
cellular chemical detoxification. Although the cytoplasmic isozyme has been characterized …

Novel FeIIIFeIII and FeIIFeIII complexes [Fe2 (BBPMP)(μ-OAc)(μ-X)] n (1, X= OAc-, n= 1+; 2,
X= OH-, n= 1+; 3, X= OAc-, n= 0; 4, X= OH-, n= 0), where BBPMP3-is the anion of 2, 6-bis [(2 …

The tartrate‐resistant acid phosphatases or purple acid phosphatases constitute a class of
related mammalian enzymes. Spectroscopic and magnetic studies have revealed that the …

A new N, O-donor binucleating ligand, 2-bis [{(2-pyridylmethyl)-aminomethyl}-{(2-
hydroxybenzyl)(2-pyridylmethyl)}-aminomethyl]-4-meth (H2BPBPMP), and its first binuclear …