Beyond Born–Oppenheimer theory for spectroscopic and scattering processes

B Mukherjee, K Naskar, S Mukherjee… - … Reviews in Physical …, 2019 - Taylor & Francis
We review our development on beyond Born–Oppenheimer (BBO) theory and its
implementation on various models and realistic molecular processes as carried out over the …

Simulations of photoinduced processes with the exact factorization: State of the art and perspectives

LM Ibele, ES Gil, EV Arribas, F Agostini - Physical Chemistry Chemical …, 2024 - pubs.rsc.org
This Perspective offers an overview of the applications of the exact factorization of the
electronnuclear wavefunction to the domain of theoretical photochemistry, where the aim is …

Beyond Born–Oppenheimer Constructed Diabatic Potential Energy Surfaces for HeH2+

K Naskar, S Ravi, S Adhikari, M Baer… - The Journal of …, 2023 - ACS Publications
First-principles based beyond Born–Oppenheimer theory has been employed to construct
multistate global Potential-Energy Surfaces (PESs) for the HeH2+ system by explicitly …

Beyond Born-Oppenheimer theory for ab initio constructed diabatic potential energy surfaces of singlet H3+ to study reaction dynamics using coupled 3D time …

S Ghosh, S Mukherjee, B Mukherjee… - The Journal of …, 2017 - pubs.aip.org
The workability of beyond Born-Oppenheimer theory to construct diabatic potential energy
surfaces (PESs) of a charge transfer atom-diatom collision process has been explored by …

Study on Quantum Dynamics of the Na + Na2 Exchanged Reaction and Lifetime Prediction of Na3 Complex Based on the Neural Network Potential Energy Surface

J Zhang, B Buren, Y Li - The Journal of Physical Chemistry A, 2024 - ACS Publications
A high-precision global potential energy surface (PES) is constructed for the Na3 system
based on high-level ab initio calculations and the fundamental invariant neural network (FI …

ADT: A Generalized Algorithm and Program for Beyond Born–Oppenheimer Equations of “N” Dimensional Sub-Hilbert Space

K Naskar, S Mukherjee, B Mukherjee… - Journal of Chemical …, 2020 - ACS Publications
The major bottleneck of first principle based beyond Born–Oppenheimer (BBO) treatment
originates from large number and complicated expressions of adiabatic to diabatic …

Conical intersections and diabatic potential energy surfaces for the three lowest electronic singlet states of H3+

S Mukherjee, D Mukhopadhyay… - The Journal of Chemical …, 2014 - pubs.aip.org
Saikat Mukherjee, Debasis Mukhopadhyay, Satrajit Adhikari; Conical intersections and
diabatic potential energy surfaces for the three lowest electronic singlet states of| ${\rm H} …

The role of electron–nuclear coupling on multi-state photoelectron spectra, scattering processes and phase transitions

J Dutta, S Mukherjee, K Naskar, S Ghosh… - Physical Chemistry …, 2020 - pubs.rsc.org
We present first principle based beyond Born–Oppenheimer (BBO) theory and its
applications on various models as well as realistic spectroscopic and scattering processes …

Construction of diabatic Hamiltonian matrix from ab initio calculated molecular symmetry adapted nonadiabatic coupling terms and nuclear dynamics for the excited …

S Mukherjee, S Bandyopadhyay, AK Paul… - The Journal of …, 2013 - ACS Publications
We present the molecular symmetry (MS) adapted treatment of nonadiabatic coupling terms
(NACTs) for the excited electronic states (22E′ and 12A1′) of Na3 cluster, where the …

Beyond Born–Oppenheimer based diabatic surfaces of 1, 3, 5-C 6 H 3 F 3+ to generate the photoelectron spectra using time-dependent discrete variable …

S Mukherjee, S Ravi, J Dutta, S Sardar… - Physical Chemistry …, 2022 - pubs.rsc.org
In this article, Beyond Born–Oppenheimer (BBO) treatment is implemented to construct
diabatic potential energy surfaces (PESs) of 1, 3, 5-C6H3F3+ over a series [eighteen (18)] of …