Review of thermal decomposition, kinetics parameters and evolved gases during pyrolysis of energetic materials using different techniques

SA El-Sayed - Journal of Analytical and Applied Pyrolysis, 2022 - Elsevier
Thermal decomposition, kinetics parameters, and evolved gases during pyrolysis of
energetic materials using different techniques have been widely studied experimentally and …

Kinetic effects of pressure on decomposition of solids

S Vyazovkin - International Reviews in Physical Chemistry, 2020 - Taylor & Francis
The kinetics of thermal decomposition of solids is discussed in connection with three major
approaches to inducing pressure: by manipulating pressure of the product gas, by changing …

[HTML][HTML] Direct numerical simulation of shear localization and decomposition reactions in shock-loaded HMX crystal

RA Austin, NR Barton, JE Reaugh… - Journal of Applied Physics, 2015 - pubs.aip.org
A numerical model is developed to study the shock wave ignition of octahydro-1, 3, 5, 7-
tetranitro-1, 3, 5, 7-tetrazocine (HMX) crystal. The model accounts for the coupling between …

Review of phase transformations in energetic materials as a function of pressure and temperature

TR Ravindran, R Rajan… - The Journal of Physical …, 2019 - ACS Publications
Under ambient conditions, energetic materials may exist in one or more than one metastable
crystal structure. Under compression or when heated, the material may transform into a …

Pressure and Polymorph Dependent Thermal Decomposition Mechanism of Molecular Materials: A Case of 1, 3, 5,-Trinitro-1, 3, 5,-triazine

C Wang, C Zhang, X Xue - The Journal of Physical Chemistry A, 2022 - ACS Publications
1, 3, 5,-Trinitro-1, 3, 5,-triazine (RDX) serves as an important energetic material and is widely
used as various solid propellants and explosives. Understanding the thermal decomposition …

Phase transitions and chemical reactions of octahydro-1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetrazocine under high pressure and high temperature

D Gao, J Huang, X Lin, D Yang, Y Wang, H Zheng - RSC advances, 2019 - pubs.rsc.org
Octahydro-1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetrazocine (HMX) is one of the most important
energetic materials. Investigations on its phase transitions and chemical reactions under …

Theoretical investigation of vibrational and electronic properties of HMX crystal under uniaxial compression

J Fan, N Gao, P Wang - Journal of Physics: Condensed Matter, 2022 - iopscience.iop.org
Abstract Octahydro-1, 3, 5, 7-tetranitro-1, 3, 5, 7-tetrazocine (HMX) is a typical energetic
molecular crystal with excellent detonation performance and good thermal stability, has …

Exploration of the hydrogen-bonded energetic material carbohydrazide at high pressures

T Yan, K Wang, X Tan, J Liu, B Liu… - The Journal of Physical …, 2014 - ACS Publications
We have reported the high-pressure behavior of hydrogen-bonded energetic material
carbohydrazide (CON4H6, CHZ) via in situ Raman spectroscopy and angle-dispersive X-ray …

Pressure-induced irreversible phase transition in the energetic material urea nitrate: combined Raman scattering and X-ray diffraction study

S Li, Q Li, K Wang, M Zhou, X Huang, J Liu… - The Journal of …, 2013 - ACS Publications
In situ high-pressure Raman spectroscopy and synchrotron X-ray diffraction (XRD) have
been employed to investigate the behavior of the energetic material urea nitrate ((NH2) …

Introduction to chemical kinetics

AK Burnham, AK Burnham - Global Chemical Kinetics of Fossil Fuels: How …, 2017 - Springer
After introducing the basis of the Arrhenius equation and its relationship to transition-state
theory, forms of global chemical kinetic models are summarized, including shrinking core …