The role of architectural engineering in macromolecular self-assemblies via non-covalent interactions: A molecular LEGO approach

Z Su, R Zhang, XY Yan, QY Guo, J Huang… - Progress in Polymer …, 2020 - Elsevier
Macromolecular self-assembly has made explosive development in the last several
decades, are being extensively explored in the fields of drug delivery, lithography, catalysis …

Macromolecular superstructures: a future beyond single chain nanoparticles

H Frisch, BT Tuten… - Israel Journal of …, 2020 - Wiley Online Library
Over the last 100 years polymer chemistry has flourished in all areas and enabled control
over synthetic polymer architectures–including chain lengths, dispersity and monomer …

Molecular Insights into [2.2] Paracyclophane‐Based Functional Materials: Chemical Aspects Behind Functions

Z Hassan - Advanced Functional Materials, 2024 - Wiley Online Library
Many of the functions and features of practically useful materials are the province of
molecular‐level chemistry and their modulation at different length‐scale. This report …

Secondary structure in nonpeptidic supramolecular block copolymers

M Milton, R Deng, A Mann, C Wang… - Accounts of Chemical …, 2021 - ACS Publications
Conspectus Proteins contain a level of complexity—secondary and tertiary structures—that
polymer chemists aim to imitate. The bottom-up synthesis of protein-mimicking polymers …

Stereoretentive Ring-Opening Metathesis Polymerization to Access All-cis Poly(p-phenylenevinylene)s with Living Characteristics

TW Hsu, C Kim, Q Michaudel - Journal of the American Chemical …, 2020 - ACS Publications
Poly (p-phenylenevinylene) s (PPVs), a staple of the conductive polymer family, consist of
alternating alkene and phenyl groups in conjugation. The physical properties of this organic …

Synthesis and Polymerization of an ortho-para-Substituted Tetraalkoxy [2.2]Paracyclophane-1,9-diene

A Mann, M Weck - ACS Macro Letters, 2022 - ACS Publications
This contribution describes the synthesis of an unsymmetrical substituted tetraalkoxy [2.2]
paracyclophane-1, 9-diene comprised of an ortho-substituted and a para-substituted …

Supramolecular multiblock copolymers featuring complex secondary structures

E Elacqua, KB Manning, DS Lye… - Journal of the …, 2017 - ACS Publications
This contribution introduces main-chain supramolecular ABC and ABB′ A block
copolymers sustained by orthogonal metal coordination and hydrogen bonding between …

Supramolecular Diblock Copolymers Featuring Well‐defined Telechelic Building Blocks

E Elacqua, A Croom, KB Manning… - Angewandte …, 2016 - Wiley Online Library
We report supramolecular AB diblock copolymers comprised of well‐defined telechelic
building blocks. Helical motifs, formed via reversible addition‐fragmentation chain‐transfer …

Cyclophanediene and Cyclophanetriene‐Based Conjugated Polymers

A Mann, MD Hannigan, M Weck - … Chemistry and Physics, 2023 - Wiley Online Library
Poly (p‐phenylene vinylene) s (PPVs) and poly (arylene vinylene) s are key materials for a
variety of applications ranging from organic light emitting diodes to fluorescent optical …

Poly (arylenevinylene) s through Ring‐Opening Metathesis Polymerization of an Unsymmetrical Donor‐Acceptor Cyclophane

E Elacqua, M Gregor - Angewandte Chemie International …, 2019 - Wiley Online Library
Reported are well‐defined donor‐acceptor alternating copolymers prepared using ring‐
opening metathesis polymerization (ROMP). Unsymmetrical cyclophanedienes comprising …