Catalysis of alloys: classification, principles, and design for a variety of materials and reactions

Y Nakaya, S Furukawa - Chemical Reviews, 2022 - ACS Publications
Alloying has long been used as a promising methodology to improve the catalytic
performance of metallic materials. In recent years, the field of alloy catalysis has made …

Intermetallic compounds: promising inorganic materials for well-structured and electronically modified reaction environments for efficient catalysis

S Furukawa, T Komatsu - Acs Catalysis, 2017 - ACS Publications
An overview of the catalytic properties of intermetallic compounds has been made to provide
a comprehensive understanding regarding (1) what intermetallic catalysts can do,(2) their …

Two-dimensional transition metal carbides as supports for tuning the chemistry of catalytic nanoparticles

Z Li, L Yu, C Milligan, T Ma, L Zhou, Y Cui, Z Qi… - Nature …, 2018 - nature.com
Supported nanoparticles are broadly employed in industrial catalytic processes, where the
active sites can be tuned by metal-support interactions (MSIs). Although it is well accepted …

Catalytic applications of early/late heterobimetallic complexes

BG Cooper, JW Napoline, CM Thomas - Catalysis Reviews, 2012 - Taylor & Francis
Transition metal complexes that combine electronically different metals are most readily
designed by combining an early transition metal and a late transition metal, typically via a …

Pt3Ti Intermetallic Alloy Formed by Strong Metal–Support Interaction over Pt/TiO2 for the Selective Hydrogenation of Acetophenone

X Zhang, W Shi, Y Li, W Zhao, S Han, W Shen - ACS Catalysis, 2023 - ACS Publications
The strong metal–support interaction over Pt/TiO2 catalysts, which were prepared by
depositing size-specified Pt colloids (2–6 nm) onto anatase TiO2 nanosheets dominated by …

The impact of synthetic method on the catalytic application of intermetallic nanoparticles

BP Williams, Z Qi, W Huang, CK Tsung - Nanoscale, 2020 - pubs.rsc.org
Intermetallic alloy nanocrystals have emerged as a promising next generation of
nanocatalyst, largely due to their promise of surface tunability. Atomic control of the …

Two-dimensional titanium carbide (MXene)-supported Pt3Ti intermetallic compound catalysts for efficient room-temperature oxidative removal of gaseous …

K Vikrant, H Yang, MW Chung, KH Kim, F Dong… - Materials Today …, 2023 - Elsevier
The potential of reactive metal–support interactions has been investigated using platinum
(Pt) and a two-dimensional titanium carbide (Ti 3 C 2 [MXene]) support to achieve the full …

Catalyst design concept based on a variety of alloy materials: a personal account and relevant studies

S Furukawa, T Komatsu, K Shimizu - Journal of Materials Chemistry A, 2020 - pubs.rsc.org
An overview of our recent advances in the development of highly efficient alloy materials for
catalytic applications (intermetallic compounds, pseudo-binary, solid-solution, and single …

Electrochemical deposition of Au–Pt alloy particles with cauliflower-like microstructures for electrocatalytic methanol oxidation

W Ye, H Kou, Q Liu, J Yan, F Zhou, C Wang - International journal of …, 2012 - Elsevier
Au–Pt alloy particles with cauliflower-like microstructures of varying Pt/Au ratios were
electrodeposited on indium tin oxide (ITO) substrates by constant potential electrolysis at …

Ammonia synthesis over Co–Mo alloy nanoparticle catalyst prepared via sodium naphthalenide-driven reduction

Y Tsuji, M Kitano, K Kishida, M Sasase… - Chemical …, 2016 - pubs.rsc.org
We report the synthesis of Co–Mo alloy nanoparticles with a uniform distribution of the alloy
elements on CeO2via sodium naphthalenide-driven reduction. The resulting sample …