Chemistry of alkaline earth metals: It is not all ionic and definitely not boring!
KM Fromm - Coordination Chemistry Reviews, 2020 - Elsevier
Some scientists might consider group 2 chemistry as “boring, closed shell and all ionic,
aqueous chemistry, where everything is known! It is not worth investigating”. How wrong …
aqueous chemistry, where everything is known! It is not worth investigating”. How wrong …
The use of mixed-metal single source precursors for the synthesis of complex metal oxides
Complex metal oxides, defined as metal oxide materials with multiple metals, phases or
including dopants, are used in a huge variety of modern applications ranging from …
including dopants, are used in a huge variety of modern applications ranging from …
High-entropy alloy screening for halide perovskites
As the concept of high-entropy alloying (HEA) extends beyond metals, new materials
screening methods are needed. Halide perovskites (HP) are a prime case study because …
screening methods are needed. Halide perovskites (HP) are a prime case study because …
Synthesis, Structure, and Luminescence of Mixed-Ligand Lanthanide Trifluoroacetates
A series of new mixed-ligand lanthanide trifluoroacetates of formula Ln (4-cpno)(tfa) 3
(H2O)· H2O (Ln= Sm, Eu, Gd, Tb, Dy; 4-cpno= 4-cyanopyridine N-oxide; tfa= trifluoroacetate) …
(H2O)· H2O (Ln= Sm, Eu, Gd, Tb, Dy; 4-cpno= 4-cyanopyridine N-oxide; tfa= trifluoroacetate) …
Reactivity of bi-and monometallic trifluoroacetates towards amorphous SiO 2
The reactivity of alkali–manganese (II) and alkali trifluoroacetates towards amorphous SiO2
(a-SiO2) was studied in the solid-state. K4Mn2 (tfa) 8, Cs3Mn2 (tfa) 7 (tfaH), KH (tfa) 2, and …
(a-SiO2) was studied in the solid-state. K4Mn2 (tfa) 8, Cs3Mn2 (tfa) 7 (tfaH), KH (tfa) 2, and …
Exploiting the Reactivity of Metal Trifluoroacetates to Access Alkali–Niobium (V) Oxyfluorides
Motivated by the lack of facile routes to alkali–niobium (V) oxyfluorides KNb2O5F and
CsNb2O5F, we investigated the reactivity of alkali trifluoroacetates KH (tfa) 2 and CsH (tfa) 2 …
CsNb2O5F, we investigated the reactivity of alkali trifluoroacetates KH (tfa) 2 and CsH (tfa) 2 …
HF-Free synthesis of colloidal Cs 2 ZrF 6 and (NH 4) 2 ZrF 6 nanocrystals
E Tzanetopoulos, J Schwartz… - Chemical Communications, 2023 - pubs.rsc.org
A solution-phase synthesis of colloidally stable A2BF6 nanocrystals is reported for the first
time, focusing on A+= Cs+, NH4+ and B4+= Zr4+. Handling hypertoxic HF is avoided by …
time, focusing on A+= Cs+, NH4+ and B4+= Zr4+. Handling hypertoxic HF is avoided by …
Organohalide precursors for the continuous production of photocatalytic bismuth oxyhalide nanoplates
Metal heteroanionic materials, such as oxyhalides, are promising photocatalysts in which
band positions can be engineered for visible-light absorption by changing the halide …
band positions can be engineered for visible-light absorption by changing the halide …
Use of heterometallic alkali metal–magnesium aryloxides in ring-opening polymerization of cyclic esters
R Petrus, T Lis, A Kowaliński - Dalton Transactions, 2022 - pubs.rsc.org
In this work, alkali metal–magnesium aryloxides [Mg2Li2 (MesalO) 6](1),[Mg2Na2 (MesalO)
6 (THF) x] for x= 2 or 4 (2), and [Mg2K2 (MesalO) 6 (THF) 4](3) derived from the reaction of …
6 (THF) x] for x= 2 or 4 (2), and [Mg2K2 (MesalO) 6 (THF) 4](3) derived from the reaction of …
Bimetallic Trifluoroacetates as Precursors to Layered Perovskites A2MnF4 (A = K, Rb, and Cs)
Four novel alkali–manganese (II) trifluoroacetates were synthesized, and their potential as
self-fluorinating precursors to layered perovskites A2MnF4 (A= K, Rb, and Cs) was …
self-fluorinating precursors to layered perovskites A2MnF4 (A= K, Rb, and Cs) was …