The synthesis, isolation, and reactivity of a cationic, geometrically constrained σ3-P
compound in the hexaphenyl-carbodiphosphoranyl-based pincer-type ligand (1+) are …

Beryllium possesses a unique amalgamation of characteristics, its electronegativity
included, that not only make it a vital component in a wide range of technical sectors and …

The reactions of anionic aluminium or gallium nucleophiles {K [E (NON)]} 2 (E= Al, 1; Ga, 2;
NON= 4, 5-bis (2, 6-diisopropylanilido)-2, 7-di tert-butyl-9, 9-dimethylxanthene) with …

Quantum chemical calculations of anions AeF−(Ae= Be–Ba) and isoelectronic group-13
molecules EF (E= B–Tl) have been carried out using ab initio methods at the CCSD (T)/def2 …

This paper discusses the legislative response to handling beryllium and its compounds as
well as the administrative regulations resulting from their classification as potential human …

How different is carbon compared to other elements in the periodic table? Can carbon
compounds be regarded as coordination complexes with carbon as the central element …

Bismuth complexes stabilized by carbon-based donor ligands are underserved by their
instability, often due to facile ligand dissociation and deleterious protonolysis. Herein, we …

Low-valent main group compounds have reactivity patterns and properties reminiscent of
transition metals. While divalent carbon compounds such as carbenes are widely studied …

The recent report of planar tetracoordinate hydrogen (ptH) in In4H+ is very intriguing in
planar hypercoordinate chemistry. Our high-level CCSD (T) calculations revealed that the …

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