Substitution of alcohols by N-nucleophiles via transition metal-catalyzed dehydrogenation
Q Yang, Q Wang, Z Yu - Chemical Society Reviews, 2015 - pubs.rsc.org
Transition metal-catalyzed substitution of alcohols by N-nucleophiles (or N-alkylation of
amines and related compounds with alcohols) avoids the use of alkylating agents by means …
amines and related compounds with alcohols) avoids the use of alkylating agents by means …
Acceptorless dehydrogenative coupling reactions with alcohols over heterogeneous catalysts
Heterogeneous catalysis for the one-pot synthesis of added-value chemicals is a growing
area in green chemistry. Among various types of organic transformations that are accessible …
area in green chemistry. Among various types of organic transformations that are accessible …
Direct synthesis of benzimidazoles by dehydrogenative coupling of aromatic diamines and alcohols catalyzed by cobalt
Herein, we present the base-metal-catalyzed dehydrogenative coupling of primary alcohols
and aromatic diamines to selectively form functionalized 2-substituted benzimidazoles …
and aromatic diamines to selectively form functionalized 2-substituted benzimidazoles …
Synthesis of pyrazines and quinoxalines via acceptorless dehydrogenative coupling routes catalyzed by manganese pincer complexes
Base-metal catalyzed dehydrogenative self-coupling of 2-amino alcohols to selectively form
functionalized 2, 5-substituted pyrazine derivatives is presented. Also, 2-substituted …
functionalized 2, 5-substituted pyrazine derivatives is presented. Also, 2-substituted …
N-Alkylation of Amines by C1–C10 Aliphatic Alcohols Using A Well-Defined Ru(II)-Catalyst. A Metal–Ligand Cooperative Approach
A Ru (II)-catalyzed efficient and selective N-alkylation of amines by C1–C10 aliphatic
alcohols is reported. The catalyst [Ru (L1a)(PPh3) Cl2](1a) bearing a tridentate redox-active …
alcohols is reported. The catalyst [Ru (L1a)(PPh3) Cl2](1a) bearing a tridentate redox-active …
[HTML][HTML] Synthesis of ruthenium complexes and their catalytic applications: A review
Ruthenium complexes are an important class that has multiple catalytic and biological
applications. Ruthenium has a remarkably broad and diversified chemical spectrum. In the …
applications. Ruthenium has a remarkably broad and diversified chemical spectrum. In the …
Borrowing Hydrogen and Acceptorless Dehydrogenative Coupling in the Multicomponent Synthesis of N‐Heterocycles: A Comparison between Base and Noble Metal …
N Hofmann, KC Hultzsch - European Journal of Organic …, 2021 - Wiley Online Library
Acceptorless dehydrogenative coupling reactions (ADC) and hydrogen transfer strategies
(HT) provide a powerful tool in the multicomponent formation of N‐heterocycles. A broad …
(HT) provide a powerful tool in the multicomponent formation of N‐heterocycles. A broad …
Zn(II)-Catalyzed Selective N-Alkylation of Amines with Alcohols Using Redox Noninnocent Azo-Aromatic Ligand as Electron and Hydrogen Reservoir
We report a sustainable and eco-friendly approach for selective N-alkylation of various
amines by alcohols, catalyzed by a well-defined Zn (II)-catalyst, Zn (La) Cl2 (1a), bearing a …
amines by alcohols, catalyzed by a well-defined Zn (II)-catalyst, Zn (La) Cl2 (1a), bearing a …
Recent advances in the synthesis of benzimidazole derivatives from the oxidative coupling of primary amines
M Largeron, KMH Nguyen - Synthesis, 2018 - thieme-connect.com
Benzimidazole belongs to the top five most commonly used five-membered aromatic
nitrogen heterocycles among US FDA approved pharmaceuticals. Over the last few years, a …
nitrogen heterocycles among US FDA approved pharmaceuticals. Over the last few years, a …
Nickel(II)–NΛNΛO Pincer Type Complex-Catalyzed N-alkylation of Amines with Alcohols via the Hydrogen Autotransfer Reaction
G Balamurugan, R Ramesh… - The Journal of Organic …, 2020 - ACS Publications
A highly sustainable catalytic protocol for the coupling of alcohols and amines for selective
monoalkylated amines using Ni (II)–NΛNΛO pincer type complexes through the borrowing …
monoalkylated amines using Ni (II)–NΛNΛO pincer type complexes through the borrowing …