Data on the structure and reactivity of different nitrenium ions are generalised and described
systematically. Various reaction pathways of these reactive intermediates resulted from their …

The thermochemistry of dissociation and elimination reactions of organogallium precursors
for the GaN chemical vapor deposition (CVD) is studied at the hybrid Hartree− Fock/density …

Cyclovoltammetrisch wurde die Kinetik der Diels-Alder-Reaktion von Cyclopentadien mit
Chinon, das auf einer Monoschicht immobilisiert war (siehe Schema), untersucht. Aus der …

Methylnitrene, the CH3N diradical, is one of the most interesting of all organic free radicals,
and it has drawn a lot of attention in both experiments [1ą5] and theory.[6ą11] As the …

A continuous tert‐butoxy (CH3) 3CO. radical beam is produced in situ by respective
pyrolysis of both (CH3) 3CONO at 115 (±0.5)° C and (CH3) 3COOC (CH3) 3 at 87 (±0.5)° C …

In situ spectroscopy and calculations agree on the characterization of the pyrolytically
produced CH3S. and CH3O. radicals. The complete HeI‐PE spectra of both radicals are in …

A nitrenium ion is a molecular species characterized by a nitrogen atom that bears a formal
positive charge and two covalent bonds. Thus the simplest example of this class of reactive …

The outcome of neutral and photoionized NCH3 2 primary products of trimethylamine
photodissociation at 193 nm is determined by combining photoionization detection with …

A continuous flowing CH 3 SS radical beam is produced in situ by pyrolysis of CH 3 SSCH 3
at 215 (±0.5)° C. An obvious and complete photoelectron (PE) spectrum of the CH 3 SS …

A continuous flowing ethylthio CH 3 CH 2 S radical is produced in situ by pyrolysis of CH 3
CH 2 SSCH 2 CH 3 at 242 (±0.5)° C in a double heater inlet system on a double chamber …