Recent advances in uranium-containing polyoxometalates
GP Yang, K Li, CW Hu - Inorganic Chemistry Frontiers, 2022 - pubs.rsc.org
Uranium-containing polyoxometalates (U-POMs), an important class of actinide cluster
compounds, are the products of the assembly of uranium or uranium and POMs. These …
compounds, are the products of the assembly of uranium or uranium and POMs. These …
Snapshots of Ce70 Toroid Assembly from Solids and Solution
Crystallization at the solid–liquid interface is difficult to spectroscopically observe and
therefore challenging to understand and ultimately control at the molecular level. The Ce70 …
therefore challenging to understand and ultimately control at the molecular level. The Ce70 …
Elucidating Actinide–Pertechnetate and Actinide–Perrhenate Bonding via a Family of Th–TcO4 and Th–ReO4 Frameworks and Solutions
Technetium-99, a β-emitter produced from 235U fission, poses a challenge for the nuclear
industry due to co-extraction of pertechnetate (TcO4–) with the actinides (An) during nuclear …
industry due to co-extraction of pertechnetate (TcO4–) with the actinides (An) during nuclear …
Two U (VI)-containing silicotungstates with sandwich structures: lewis acid–base synergistic catalyzed synthesis of benzodiazepines and pyrazoles
J Zhou, T Yu, K Li, K Zeng, GP Yang… - Inorganic Chemistry, 2022 - ACS Publications
Two new U (VI)-containing silicotungstates with similar sandwiched polyanions but different
space structures, two-dimensional Na10. 5H3. 5 (H2O) 36 [Na (UO2)(α-SiW9O34)] 2· 2.5 …
space structures, two-dimensional Na10. 5H3. 5 (H2O) 36 [Na (UO2)(α-SiW9O34)] 2· 2.5 …
Effect of Na(I)-H2O clusters on self-assembly of sandwich-type U(VI)-containing silicotungstates and the efficient catalytic activity for the synthesis of substituted phenylsulfonyl-1 …
K Li, XL Lin, K Zeng, XF Gao, W Cen, YF Liu, GP Yang - Tungsten, 2022 - Springer
In this study, a sandwich-type uranium (VI)-containing silicotungstate KNa 11 H 2 (H 2 O) 30
[Na (UO 2)(SiW 9 O 34)] 2· 8H 2 O (1) with new three-dimensional (3D) structure was …
[Na (UO 2)(SiW 9 O 34)] 2· 8H 2 O (1) with new three-dimensional (3D) structure was …
Aqueous Speciation of Tetravalent Actinides in the Presence of Chloride and Nitrate Ligands
Speciation of hexachloride tetravalent uranium, neptunium, and plutonium species in
aqueous media has been investigated using density functional theory in the presence of …
aqueous media has been investigated using density functional theory in the presence of …
Elucidating trends in synthesis and structural periodicity in a series of tetravalent actinide–oxo hexamers
TL McCusker, NA Vanagas, JES Szymanowski… - …, 2025 - pubs.rsc.org
Metal ion hydrolysis and condensation reactions are critical to describing the chemical
behavior of the tetravalent actinides (An) due to their high charge density. This recognition …
behavior of the tetravalent actinides (An) due to their high charge density. This recognition …
Th(IV) Bromide Complexes: A Homoleptic Aqua Ion and a Novel Th(H2O)4Br4 Structural Unit
A Blanes-Díaz, O Stewart Jr, M Vasiliu… - Crystal Growth & …, 2022 - ACS Publications
The synthesis and structural chemistry of two tetravalent thorium compounds precipitated
from acidic bromide solutions are described. One of the phases,[Th (H2O) 10] Br4 (1), has …
from acidic bromide solutions are described. One of the phases,[Th (H2O) 10] Br4 (1), has …
[U(NH3)10]4+ Cations in Azide, Bromide, and Iodide Ammoniates and a Hydrolysis Product with an unprecedented [U(H2O)9]4+ Cation
SS Rudel, HL Deubner, TG Müller… - Zeitschrift für …, 2022 - Wiley Online Library
Abstract [U (NH3) 10] 4+ cations with bicapped square‐antiprismatic coordination spheres
were discovered in the compounds [U (NH3) 10] I4⋅ 17.37 NH3,[U (NH3) 10] I4⋅ 9NH3,[U …
were discovered in the compounds [U (NH3) 10] I4⋅ 17.37 NH3,[U (NH3) 10] I4⋅ 9NH3,[U …
Hydrolysis and Complex Formation of Cerium (IV) with Dioxysuccinic Acid in Sulfate Solutions
OO Voskresenskaya - Russian Journal of Inorganic Chemistry, 2022 - Springer
Cerium (IV) hydrolysis in sulfate solutions is studied spectrophoto-and photometrically, pH-
metrically and potentiometrically at the ionic strength I= 2 in the pH range 0.2–3.0 at 294.95 …
metrically and potentiometrically at the ionic strength I= 2 in the pH range 0.2–3.0 at 294.95 …