Cross-electrophile coupling (XEC), defined by us as the cross-coupling of two different σ-
electrophiles that is driven by catalyst reduction, has seen rapid progression in recent years …

Methyl groups are well understood to play a critical role in pharmaceutical molecules,
especially those bearing saturated heterocyclic cores. Accordingly, methods that install …

Metallaphotoredox cross-coupling is a well-established strategy for generating clinically
privileged aliphatic scaffolds via single-electron reactivity. Correspondingly, expanding …

Although screening technology has heavily impacted the fields of metal catalysis and drug
discovery, its application to the discovery of new catalyst classes has been limited. The …

N− O σ bonds containing compounds are versatile substrates for organic synthesis under
transition metal catalysis. Their ability to react through both polar (oxidative addition …

In this article, we provide a route to transform isoxazoles and oxadiazoles into the
corresponding pyrazoles and 1, 2, 4-triazoles in one step using catalytic amounts of an air …

A nickel-catalysed C–N cross-coupling of organoboronic acids and isoxazoles has been
established for the efficient synthesis of (Z) N-aryl β-enamino esters. 5-Alkoxy/phenoxy …

Presented herein is a nickel-catalyzed chemo-and regioselective three-component tandem
carboamination and cyclization of terminal alkynes with organoboronic acids and anthranils …

Abstract Poly (3‐hexylthiophene)(P3HT) is a well‐studied conjugated polymer; however, the
end‐group functionalization of these polymers is limited by fundamental synthetic …

The synthesis and catalytic properties of Ni (II) complexes, with the general formula Ni
(NHC)[P (OR) 3](Ar) Cl is described. These complexes are air-stable and extremely effective …